Effect of Operational Parameters on the Degradation of Methylene Blue Using Visible Light Active BiVO4 Photocatalyst

被引:25
作者
Arumugam, Malathi [1 ,2 ]
Choi, Myong Yong [1 ,2 ]
机构
[1] Gyeongsang Natl Univ, Dept Chem BK21, Jinju 52828, South Korea
[2] Gyeongsang Natl Univ, Res Inst Nat Sci, Jinju 52828, South Korea
基金
新加坡国家研究基金会;
关键词
BiVO4; nanoparticles; Semiconductor; Methylene blue; Visible light; Degradation; MICROWAVE-ASSISTED SYNTHESIS; HYDROTHERMAL SYNTHESIS; DRIVEN; NANOSTRUCTURES; PERFORMANCE; DYES;
D O I
10.1002/bkcs.11972
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Visible light active bismuth vanadate (BiVO4) nanoparticles were fabricated by the facile hydrothermal method. The crystal structure and formation of the prepared BiVO4 were examined by X-ray diffraction and Fourier-transform infrared spectroscopy. The optical absorption property of BiVO4 was measured by ultraviolet-vis diffuse reflectance spectroscopy. The photocatalytic activity of the as-prepared BiVO4 photocatalyst was assessed for the photodegradation of methylene blue (MB) under visible light irradiation (VLI). About 91.9% degradation in 90 min was observed when BiVO4 was used as a photocatalyst. Furthermore, the effect of varying the experimental parameters such as the catalyst amount, pH, and dye concentration were studied. Finally, the possible mechanism for MB degradation is presented.
引用
收藏
页码:304 / 309
页数:6
相关论文
共 37 条
[1]   Reactive dyes decolourization from an aqueous solution by combined coagulation/micellar-enhanced ultrafiltration process [J].
Ahmad, A. L. ;
Puma, S. W. .
CHEMICAL ENGINEERING JOURNAL, 2007, 132 (1-3) :257-265
[2]   Rapid Synthesis of Ultrahigh Adsorption Capacity Zirconia by a Solution Combustion Technique [J].
Deshpande, Parag A. ;
Polisetti, Sneha ;
Madras, Giridhar .
LANGMUIR, 2011, 27 (07) :3578-3587
[3]   Selective sorption and subsequent photocatalytic degradation of cationic dyes by sonochemically synthesized nano CuWO4 and Cu3Mo2O9 [J].
Dutta, Dimple P. ;
Rathore, Anjali ;
Ballal, Anand ;
Tyagi, A. K. .
RSC ADVANCES, 2015, 5 (115) :94866-94878
[4]   Time-resolved random laser spectroscopy of inhomogeneously broadened systems [J].
Fernandez, Joaquin ;
Garcia-Revilla, Sara ;
Carlos, Luis D. ;
Pecoraro, Edison ;
Arriandiaga, Maria A. ;
Balda, Rolindes .
LASER & PHOTONICS REVIEWS, 2014, 8 (03) :L32-L36
[5]   Photocatalytic decolorization of methylene blue in the presence of TiO2/ZnS nanocomposites [J].
Franco, A. ;
Neves, M. C. ;
Ribeiro Carrott, M. M. L. ;
Mendonca, M. H. ;
Pereira, M. I. ;
Monteiro, O. C. .
JOURNAL OF HAZARDOUS MATERIALS, 2009, 161 (01) :545-550
[6]   Transition metal tungstates synthesized by co-precipitation method: Basic photocatalytic properties [J].
Garcia-Perez, U. M. ;
Martinez-de la Cruz, A. ;
Peral, J. .
ELECTROCHIMICA ACTA, 2012, 81 :227-232
[7]   Sunlight-driven degradation of Rhodamine B by peanut-shaped porous BiVO4 nanostructures in the H2O2-containing system [J].
Ge, Ming ;
Liu, Lu ;
Chen, Wei ;
Zhou, Zhen .
CRYSTENGCOMM, 2012, 14 (03) :1038-1044
[8]   Photochemical degradation of the hazardous dye Safranin-T using TiO2 catalyst [J].
Gupta, V. K. ;
Jain, Rajeev ;
Mittal, Alok ;
Mathur, Megha ;
Sikarwar, Shalini .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2007, 309 (02) :464-469
[9]   Photoelectrochemical water splitting using visible-light-responsive BiVO4 fine particles prepared in an aqueous acetic acid solution [J].
Iwase, Akihide ;
Kudo, Akihiko .
JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (35) :7536-7542
[10]   High-performance porous spherical or octapod-like single-crystalline BiVO4 photocatalysts for the removal of phenol and methylene blue under visible-light illumination [J].
Jiang, Haiyan ;
Meng, Xue ;
Dai, Hongxing ;
Deng, Jiguang ;
Liu, Yuxi ;
Zhang, Lei ;
Zhao, Zhenxuan ;
Zhang, Ruzhen .
JOURNAL OF HAZARDOUS MATERIALS, 2012, 217 :92-99