Syntheses and chemistry of methylantimony and methylbismuth dihalides:: An extended two-dimensional framework in the crystal structure of CH3BiCl2 and molecular units in the structures of [CH3ECl2(2,2′-bipyridine)] (E = Sb, Bi)

被引：24

作者：

Althaus, H ^{[1
]}

Breunig, HJ ^{[1
]}

Lork, E ^{[1
]}

机构：

[1] Univ Bremen, Inst Anorgan & Phys Chem FB 02, D-28334 Bremen, Germany

来源：

ORGANOMETALLICS | 2001年 / 20卷 / 03期

关键词：

Alkylation - Antimony compounds - Bismuth compounds - Chemistry - Crystal structure - Ethers - Solutions - Synthesis (chemical) - X ray crystallography;

D O I：

10.1021/om000749i

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

CH3SbPh2 reacts with HCl to give CH3SbCl2. CH3BiCl2 and CH3BiBr2 are formed by reaction of CH3BiPh2 with HCl or HBr. The adducts [CH3ECl2(bipy)] (E = Sb, Bi, bipy = 2,2'-bipyridine) are obtained by combining the components in diethyl ether or tetrahydrofuran. The crystal structures of CH3BiCl2 and [CH3-ECl2(bipy)] (E = Sb, Bi) have been determined by single-crystal X-ray diffraction.

引用

页码：586 / 589

页数：4

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