Chromogenic macrocyclic derivatives of azoles-synthesis and properties

被引：31

作者：

Wagner-Wysiecka, E ^{[1
]}

Luboch, E ^{[1
]}

Kowalczyk, M ^{[1
]}

Biernat, JF ^{[1
]}

机构：

[1] Gdansk Univ Technol, Dept Chem Technol, PL-80952 Gdansk, Poland

来源：

TETRAHEDRON | 2003年 / 59卷 / 24期

关键词：

chromoionophores; azole azocrown ethers; synthesis; complexes; spectrophotometric reagents; ion-selective membrane; electrodes; X-ray structure;

D O I：

10.1016/S0040-4020(03)00618-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of macrocyclic chromogenic derivatives of pyrrole and imidazole is described. The complexing properties of these compounds with metal cations were investigated spectrophotometrically in acetonitrile. The synthesized crown ethers were also tested as ion carriers in ion-selective membrane electrodes. The X-ray structure of one isomer of 18-membered pyrrole crown ether is reported. (C) 2003 Elsevier Science Ltd. All rights reserved.

引用

页码：4415 / 4420

页数：6

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