Palladium-containing perovskites: recoverable and reuseable catalysts for Suzuki couplings

被引：90

作者：

Smith, MD ^{[1
]}

Stepan, AF ^{[1
]}

Ramarao, C ^{[1
]}

Brennan, PE ^{[1
]}

Ley, SV ^{[1
]}

机构：

[1] Univ Cambridge, Dept Chem, Chem Lab, Cambridge CB2 1EW, England

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 21期

关键词：

D O I：

10.1039/b308465e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Palladium-containing perovskites (LaFe0.57Co0.38Pd0.5O3) have been exploited as recoverable and reuseable catalysts in Suzuki coupling reactions; residual levels of Pd after removal of the catalyst by filtration are low (2 ppm) despite evidence that the reaction is occurring via a homogeneous process.

引用

页码：2652 / 2653

页数：2

共 6 条

[1] Extremely high activity catalysts for the Suzuki coupling of aryl chlorides: the importance of catalyst longevity [J].

Bedford, RB ;

Hazelwood, SL ;

Limmert, ME .

CHEMICAL COMMUNICATIONS, 2002, (22) :2610-2611

[2] Are heterogeneous catalysts precursors to homogeneous catalysts? [J].

Davies, IW ;

Matty, L ;

Hughes, DL ;

Reider, PJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (41) :10139-10140

[3] Rapid and amenable Suzuki coupling reaction in water using microwave and conventional heating [J].

Leadbeater, NE ;

Marco, M .

JOURNAL OF ORGANIC CHEMISTRY, 2003, 68 (03) :888-892

[4] On the nature of the 'heterogeneous' catalyst: Nickel-on-charcoal [J].

Lipshutz, BH ;

Tasler, S ;

Chrisman, W ;

Spliethoff, B ;

Tesche, B .

JOURNAL OF ORGANIC CHEMISTRY, 2003, 68 (04) :1177-1189

[5] Self-regeneration of a Pd-perovskite catalyst for automotive emissions control [J].

Nishihata, Y ;

Mizuki, J ;

Akao, T ;

Tanaka, H ;

Uenishi, M ;

Kimura, M ;

Okamoto, T ;

Hamada, N .

NATURE, 2002, 418 (6894) :164-167

[6] A review of the problem of distinguishing true homogeneous catalysis from soluble or other metal-particle heterogeneous catalysis under reducing conditions [J].

Widegren, JA ;

Finke, RG .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2003, 198 (1-2) :317-341

← 1 →