Morphological tuning and conductivity of organic conductor nanowires

被引:37
作者
Liu, Huibiao [1 ]
Li, Junbo [1 ]
Lao, Changshi [2 ]
Huang, Changshui [1 ]
Li, Yuliang [1 ]
Wang, Zhong Lin [2 ]
Zhu, Daoben [1 ]
机构
[1] Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, CAS Key Lab Organ Solid, Beijing 100080, Peoples R China
[2] Georgia Inst Technol, Sch Mat Sci, Atlanta, GA 30332 USA
关键词
D O I
10.1088/0957-4484/18/49/495704
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
We report the synthesis of small-molecule organic conductor nanowires of TTF-TCNQ by selective inducement in a two-phase method by pi-pi stacking interaction. The morphologies of TTF-TCNQ, from straight nanowires to helical nanowires and to complicated helical dendrite structures, have been controlled by adjusting the experimental conditions. The technique has been applied to the synthesis of AgTCNQ/CuTCNQ nanowires in a two-phase system of acetonitrile/hexane. I-V characterization of an individual nanowire indicated that the conductivity along the b-axis of the TTF-TCNQ helical nanowire is much better than that along other directions. The synthetic procedure presented is a general approach for producing controlled organic conductor/semiconductor nanowires.
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页数:7
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