Borassus flabellifer Fruit Flesh Derived Hierarchical Porous Partly Graphitic Carbon as a Sustainable Electrode for Supercapacitors

被引:14
作者
Saha, Shalakha [1 ]
Potphode, Darshna [1 ,2 ]
Sharma, Chandra S. [1 ]
机构
[1] Indian Inst Technol, Dept Chem Engn, Creat & Adv Res Based Nanomat CARBON Lab, Hyderabad Kandi 502285, Telangana, India
[2] Univ Mumbai, Dept Chem, Mumbai 400098, Maharashtra, India
关键词
HIGH-ENERGY-DENSITY; ACTIVATED CARBON; NAOH ACTIVATION; SURFACE-AREA; PERFORMANCE; NANOSHEETS; NITROGEN; OXYGEN; KOH; STORAGE;
D O I
10.1021/acs.energyfuels.1c03235
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
The present work provides a straightforward two-step strategy of carbonization, followed by KOH activation, for transforming Borassus flabellifer fruit flesh, one of the cost-effective and sustainable lignocellulose biomass to porous activated carbon for utilization in energy storage systems. The acquired activated Borassus flabellifer fruit flesh (ABFF) carbon exhibits features like high surface area (similar to 1087.8 m(2) g(-1)) with surface functionalities, hierarchical porous morphology (presence of micropores and mesopores), together with some partially graphitic domain, some of the prerequisites for demonstration of excellent electrochemical performance. Taking advantage of the structural features and chemical composition, the ABFF carbon, when assembled in a symmetrical two-electrode configuration, exhibits an impressive specific capacitance of 226 F g(-1) and 159 F g(-1) in 1 M H2SO4 and neat ionic liquid (IL) EMIMBF4 electrolyte. The as-fabricated symmetric device attained a maximum energy density of 8 Wh kg(-1) in the aqueous medium, while an enhanced energy density of 50 Wh kg(-1) was achieved in the nonaqueous medium.
引用
收藏
页码:638 / 654
页数:17
相关论文
共 86 条
  • [31] MOF-derived NixCo1-x(OH)2 composite microspheres for high-performance supercapacitors
    He, Shuhua
    Li, Zhangpeng
    Wang, Jinqing
    Wen, Ping
    Gao, Jiechang
    Ma, Limin
    Yang, Zhigang
    Yang, Shengrong
    [J]. RSC ADVANCES, 2016, 6 (55) : 49478 - 49486
  • [32] Efficient preparation of biomass-based mesoporous carbons for supercapacitors with both high energy density and high power density
    He, Xiaojun
    Ling, Pinghua
    Qiu, Jieshan
    Yu, Moxin
    Zhang, Xiaoyong
    Yu, Chang
    Zheng, Mingdong
    [J]. JOURNAL OF POWER SOURCES, 2013, 240 : 109 - 113
  • [33] Analysis of graphene-like activated carbon derived from rice straw for application in supercapacitor
    Horax, Kevin Monthiego
    Bao, Shujuan
    Wang, Minqiang
    Li, Yanan
    [J]. CHINESE CHEMICAL LETTERS, 2017, 28 (12) : 2290 - 2294
  • [34] Hierarchical Porous Nitrogen-Doped Carbon Nanosheets Derived from Silk for Ultrahigh-Capacity Battery Anodes and Supercapacitors
    Hou, Jianhua
    Cao, Chuanbao
    Idrees, Faryal
    Ma, Xilan
    [J]. ACS NANO, 2015, 9 (03) : 2556 - 2564
  • [35] Natural Biomass-Derived Hierarchical Porous Carbon Synthesized by an in Situ Hard Template Coupled with NaOH Activation for Ultrahigh Rate Supercapacitors
    Hu, Longfeng
    Zhu, Qizhen
    Wu, Qi
    Li, Dongsheng
    An, Zhongxun
    Xu, Bin
    [J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2018, 6 (11): : 13949 - 13959
  • [36] Promising nature-based activated carbon derived from flowers of Borassus flabellifer for supercapacitor applications
    Iro, Zaharaddeen S.
    Subramani, C.
    Rajendran, Jerome
    Sundramoorthy, Ashok K.
    [J]. CARBON LETTERS, 2021, 31 (06) : 1145 - 1153
  • [37] Jena L., 2021, CURR RES GREEN SUSTA, V4, P100077, DOI [10.1016/j.crgsc.2021.100077, DOI 10.1016/J.CRGSC.2021.100077]
  • [38] Construction of High-Energy-Density Supercapacitors from Pine-Cone-Derived High-Surface-Area Carbons
    Karthikeyan, Kaliyappan
    Amaresh, Samuthirapandiyan
    Lee, Sol Nip
    Sun, Xueliang
    Aravindan, Vanchiappan
    Lee, Young-Gi
    Lee, Yun Sung
    [J]. CHEMSUSCHEM, 2014, 7 (05) : 1435 - 1442
  • [39] Electrochemical Capacitors Based on Electrodes Made of Lignocellulosic Waste Materials
    Kolanowski, L.
    Gras, M.
    Bartkowiak, M.
    Doczekalska, B.
    Lota, G.
    [J]. WASTE AND BIOMASS VALORIZATION, 2020, 11 (07) : 3863 - 3871
  • [40] Krishnaveni T. S., 2020, ADV RES, V21, P29, DOI [DOI 10.9734/AIR/2020/V21I930229, 10.9734/air/2020/v21i930229]