Synthesis, structure and luminescent property of a pillared-layer coordination polymer [Pb(BPDC)] (BPDC=4,4′-biphenyldicarboxylate)

被引：21

作者：

Hu, Ranran ^{[1
,2
]}

Cai, Hu ^{[1
]}

Luo, Junhua ^{[2
]}

机构：

[1] Nanchang Univ, Dept Chem, Nanchang 330031, Jiangxi, Peoples R China

[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Optoelect Mat Chem & Phys, Fuzhou 350002, Fujian, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2011年 / 14卷 / 02期

关键词：

Pb(II); 4,4 '-biphenyldicarboxylic acid; Pillared Framework; Luminescence; Crystal Structure; METAL-ORGANIC FRAMEWORKS; HYDROTHERMAL SYNTHESIS; CRYSTAL-STRUCTURES; LIGANDS; COMPLEXES; TOPOLOGY; ACID; 3D; NETWORK; PHOTOLUMINESCENCE;

D O I：

10.1016/j.inoche.2010.12.021

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new 3D pillared framework has been obtained through self-assembly of 4,4'-biphenyldicarboxylic acid (4,4'-H2BPDC) and Pb(NO3)(2) under solvothermal reaction and characterized by TGA, IR spectroscopy, element analyses, and X-ray single crystal diffraction. The X-ray structure analysis reveals that the oxygen atoms of the carboxylate groups link the Pb(II) to form metal-carboxylate layers, and 4,4'-BPDC ligands act as pillars to connect adjacent layers into a novel 3D pillared framework, where the BPDC displayed a rare mu(6) coordination mode of each BPDC linking with six Pb(II) ions. Furthermore, the highly thermally stable compound 1 exhibits blue photoluminescence at room temperature in the solid state. Crown Copyright (C) 2010 Published by Elsevier B.V. All rights reserved.

引用

页码：433 / 436

页数：4

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