Synthesis, structure and luminescent property of a pillared-layer coordination polymer [Pb(BPDC)] (BPDC=4,4′-biphenyldicarboxylate)

被引：21

作者：

Hu, Ranran ^{[1
,2
]}

Cai, Hu ^{[1
]}

Luo, Junhua ^{[2
]}

机构：

[1] Nanchang Univ, Dept Chem, Nanchang 330031, Jiangxi, Peoples R China

[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Optoelect Mat Chem & Phys, Fuzhou 350002, Fujian, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2011年 / 14卷 / 02期

关键词：

Pb(II); 4,4 '-biphenyldicarboxylic acid; Pillared Framework; Luminescence; Crystal Structure; METAL-ORGANIC FRAMEWORKS; HYDROTHERMAL SYNTHESIS; CRYSTAL-STRUCTURES; LIGANDS; COMPLEXES; TOPOLOGY; ACID; 3D; NETWORK; PHOTOLUMINESCENCE;

D O I：

10.1016/j.inoche.2010.12.021

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new 3D pillared framework has been obtained through self-assembly of 4,4'-biphenyldicarboxylic acid (4,4'-H2BPDC) and Pb(NO3)(2) under solvothermal reaction and characterized by TGA, IR spectroscopy, element analyses, and X-ray single crystal diffraction. The X-ray structure analysis reveals that the oxygen atoms of the carboxylate groups link the Pb(II) to form metal-carboxylate layers, and 4,4'-BPDC ligands act as pillars to connect adjacent layers into a novel 3D pillared framework, where the BPDC displayed a rare mu(6) coordination mode of each BPDC linking with six Pb(II) ions. Furthermore, the highly thermally stable compound 1 exhibits blue photoluminescence at room temperature in the solid state. Crown Copyright (C) 2010 Published by Elsevier B.V. All rights reserved.

引用

页码：433 / 436

页数：4

共 57 条

[1] A new double-Keggin-anion-templated organic-inorganic hybrid architecture: Synthesis, crystal structure and photoluminescence [J].

An, Haiyan ;

Xu, Tieqi ;

Zheng, Hui ;

Han, Zhengbo .

INORGANIC CHEMISTRY COMMUNICATIONS, 2010, 13 (02) :302-305

[2] Cation-Triggered Drug Release from a Porous Zinc-Adeninate Metal-Organic Framework [J].

An, Jihyun ;

Geib, Steven J. ;

Rosi, Nathaniel L. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (24) :8376-+

[3]

[Anonymous], 1997, SHELXTL 97 PROGRAM S

[4] Luminescence of nanocrystalline ZnS:Pb2+ [J].

Bol, AA ;

Meijerink, A .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2001, 3 (11) :2105-2112

[5] Coordination polymers constructed by linking metal ions with azodibenzoate anions [J].

Chen, Zhen-Feng ;

Zhang, Zhi-Li ;

Tan, Yu-Hui ;

Tang, Yun-Zhi ;

Fun, Hoong-Kun ;

Zhou, Zhong-Yuan ;

Abrahams, Brendan F. ;

Liang, Hong .

CRYSTENGCOMM, 2008, 10 (02) :217-231

[6] Coordination polymers composed of copper(II), trimesic acid, and imidazole: 3D architecture stabilized by hydrogen bonding [J].

Cheng, DP ;

Khan, MA ;

Houser, RP .

INORGANIC CHEMISTRY, 2001, 40 (27) :6858-+

[7] Strong H2 binding and selective gas adsorption within the microporous coordination solid Mg3(O2C-C10H6-CO2)3 [J].

Dinca, M ;

Long, JR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (26) :9376-9377

[8] Lead as its own luminescent sensor [J].

Dutta, SK ;

Perkovic, MW .

INORGANIC CHEMISTRY, 2002, 41 (26) :6938-6940

[9] Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage [J].

Eddaoudi, M ;

Kim, J ;

Rosi, N ;

Vodak, D ;

Wachter, J ;

O'Keeffe, M ;

Yaghi, OM .

SCIENCE, 2002, 295 (5554) :469-472

[10] Crystal engineering of NLO materials based on metal-organic coordination networks [J].

Evans, OR ;

Lin, WB .

ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (07) :511-522

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