Photo-Fenton degradation of phenol by CdS/rGO/Fe2+ at natural pH with in situ-generated H2O2

被引：208
作者：
Jiang, Zhenying [1 ,2 ]
Wang, Lingzhi [1 ,2 ]
Lei, Juying [3 ,4 ]
Liu, Yongdi [3 ,4 ]
Zhang, Jinlong [1 ,2 ]
机构：
[1] East China Univ Sci & Technol, Key Lab Adv Mat, 130 Meilong Rd, Shanghai 200237, Peoples R China
[2] East China Univ Sci & Technol, Inst Fine Chem, 130 Meilong Rd, Shanghai 200237, Peoples R China
[3] East China Univ Sci & Technol, State Environm Protect Key Lab Environm Risk Asse, Sch Resources & Environm Engn, 130 Meilong Rd, Shanghai 200237, Peoples R China
[4] Shanghai Inst Pollut Control & Ecol Secur, Shanghai 200092, Peoples R China
来源：
APPLIED CATALYSIS B-ENVIRONMENTAL | 2019年 / 241卷
关键词：
In sins generation of H2O2; Fenton; Degradation; Natural pH; Phenol; GRAPHITIC CARBON NITRIDE; WASTE-WATER TREATMENT; HYDROGEN-PEROXIDE; GRAPHENE OXIDE; PHOTOCATALYTIC ACTIVITY; QUANTUM DOTS; NEUTRAL PH; OXIDATION; G-C3N4; COMPOSITE;
D O I：
10.1016/j.apcatb.2018.09.049
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The application of photo-Fenton process is restricted by the acidic pH and additional hydrogen peroxide (H2O2). In order to overcome these drawbacks, a photo-Fenton system of CdS/rGO/Fe2+ which can perform at natural pH with in situ-generated H2O2 has been successfully developed. Highly efficient photo-Fenton degradation of phenol was achieved under the visible light irradiation via the CdS/rGO/Fe2+ system. Experimental results showed that phenol could be degraded completely in 1 h at natural pH. The plentiful in situ generation of H2O2 was further proved to act as an important role in phenol degradation with the addition of Fe2+. The advantages of degradation at natural pH with in situ-generated H2O2 can provide a new prospective to the environmental-friendly Fenton process.
引用
收藏
页码：367 / 374
页数：8
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