Selective removal of cesium from acid solutions with immobilized copper ferrocyanide

被引:42
|
作者
Clarke, TD [1 ]
Wai, CM [1 ]
机构
[1] Univ Idaho, Dept Chem, Moscow, ID 83844 USA
关键词
D O I
10.1021/ac971138b
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Copper ferrocyanide can be immobilized on Chelex-20, a technical grade chelating resin, for selective removal of cesium from neutral to acidic solutions. The immobilized copper ferrocyanide is much easier to handle than the copper ferrocyanide powder in extraction and separation of cesium from aqueous solutions. In the presence of a reducing agent such as hydrazine, the immobilized copper ferrocyanide resin is able to remove 98% of the cesium from a simulated acid waste solution in one cycle of batch experiments. The resin shows promising properties for remediation of acidic nuclear wastes and for concentration of Cs-137 from environmental samples for quantitative analysis.
引用
收藏
页码:3708 / 3711
页数:4
相关论文
共 50 条
  • [1] Removal of radioactive cesium from solutions by zinc ferrocyanide
    LI Bing~1 LIAO Jiali~1 WU Jiaojiao~1 ZHANG Dong~2 ZHAO Jun~2 YANG Yuanyou~1 CHENG Qiong~2 FENG Yue~1 LIU Ning~(1
    Nuclear Science and Techniques, 2008, (02) : 88 - 92
  • [2] Removal of radioactive cesium from solutions by zinc ferrocyanide
    Li Bing
    Liao Jiali
    Wu Jiaojiao
    Zhang Dong
    Zhao Jun
    Yang Yuanyou
    Cheng Qiong
    Feng Yue
    Liu Ning
    NUCLEAR SCIENCE AND TECHNIQUES, 2008, 19 (02) : 88 - 92
  • [3] Copper Ferrocyanide-Functionalized Magnetic Nanoparticles for the Selective Removal of Radioactive Cesium
    Yang, Hee-Man
    Lee, Kune-Woo
    Seo, Bum-Kyoung
    Moon, Jei-Kwon
    JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2015, 15 (02) : 1695 - 1699
  • [4] A REVIEW OF INFORMATION ON FERROCYANIDE SOLIDS FOR REMOVAL OF CESIUM FROM SOLUTIONS
    HAAS, PA
    SEPARATION SCIENCE AND TECHNOLOGY, 1993, 28 (17-18) : 2479 - 2506
  • [5] Facile synthesis of potassium copper ferrocyanide composite particles for selective cesium removal from wastewater in the batch and continuous processes
    Zong, Youli
    Zhang, Yongde
    Lin, Xiaoyan
    Ye, Dong
    Qiao, Dan
    Zeng, Shuangneng
    RSC ADVANCES, 2017, 7 (50) : 31352 - 31364
  • [6] PREPARATION METHODS OF COPPER-FERROCYANIDE FUNCTIONALIZED MAGNETIC NANOPARTICLES FOR SELECTIVE REMOVAL OF CESIUM IN AQUEOUS SOLUTION
    Yang, Hee-Man
    Lee, Kune Woo
    Seo, Bum-Kyoung
    Moon, Jei Kwon
    ASME 2013 15TH INTERNATIONAL CONFERENCE ON ENVIRONMENTAL REMEDIATION AND RADIOACTIVE WASTE MANAGEMENT, VOL 2: FACILITY DECONTAMINATION AND DECOMMISSIONING; ENVIRONMENTAL REMEDIATION; ENVIRONMENTAL MANAGEMENT/PUBLIC INVOLVEMENT/CROSSCUTTING ISSUES/GLOBAL PARTNERING, 2013,
  • [7] Copper ferrocyanide chemically immobilized onto a polyvinylidene fluoride hollow-fibre membrane surface for the removal of aqueous cesium
    Lee, Hyun-Kyu
    Choi, Sang-June
    ENVIRONMENTAL TECHNOLOGY, 2022, 43 (15) : 2241 - 2251
  • [8] Investigation of coagulation as a pretreatment for microfiltration in cesium removal by copper ferrocyanide adsorption
    Xu, Yao
    Gu, Ping
    Zhang, GuangHui
    Wang, XuQian
    JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 2017, 313 (02) : 435 - 444
  • [9] Investigation of coagulation as a pretreatment for microfiltration in cesium removal by copper ferrocyanide adsorption
    Yao Xu
    Ping Gu
    GuangHui Zhang
    XuQian Wang
    Journal of Radioanalytical and Nuclear Chemistry, 2017, 313 : 435 - 444
  • [10] Magnetic hierarchical titanium ferrocyanide for the highly efficient and selective removal of radioactive cesium from water
    Yang H.-M.
    Sihn Y.
    Kim I.
    Park C.W.
    Chemosphere, 2024, 353