1-[5-(Anthracen-9-yl)-3-phenyl-4,5-dihydro-1H-pyrazol-1-yl]ethanone

被引:5
|
作者
Wang, Ming-Liang [1 ]
Dong, Bao-Li [1 ]
Li, Yong-Hua [1 ]
机构
[1] Southeast Univ, Sch Chem & Chem Engn, Nanjing 211189, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词
D O I
10.1107/S160053681005018X
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, C25H20N2O, the pyrazoline ring is nearly planar [maximum atomic deviation = 0.0254 (17) angstrom]; but the anthracene ring system is distorted from a coplanar structure [maximum atomic deviation = 0.181 (3) angstrom], the dihedral angle between the outer benzene rings being 10.68 (13)degrees. The pyrazoline ring is almost perpendicular to the mean plane of the anthracene ring system [dihedral angle = 76.94 (8)degrees], but nearly coplanar with the phenyl ring [dihedral angle = 1.63 (7)degrees]. pi-pi stacking is observed between parallel benzene rings of adjacent anthracene units, the faceto- face distance being 3.27 (3) angstrom. Weak intramolecular C-H center dot center dot center dot N hydrogen bonding also occurs.
引用
收藏
页码:O94 / U2170
页数:9
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