Metal organic frameworks with immobilized nanoparticles: Synthesis and applications in photocatalytic hydrogen generation and energy storage

被引:50
作者
Railey, Prescott [1 ]
Song, Yu [1 ]
Liu, Tianyu [1 ]
Li, Yat [1 ]
机构
[1] Univ Calif Santa Cruz, Dept Chem & Biochem, Santa Cruz, CA 95064 USA
关键词
Metal-organic frameworks; Nanoparticles; Synthesis; Photo-catalysis; Energy storage; AT-MOF COMPOSITES; HIGHLY EFFICIENT; PALLADIUM NANOPARTICLES; COORDINATION POLYMERS; PD NANOPARTICLES; SURFACE; FABRICATION; ADSORPTION; OXIDATION; CATALYSTS;
D O I
10.1016/j.materresbull.2017.04.020
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Composite materials consisting of metal-organic frameworks (MOFs) and immobilized nanoparticles (NP@MOFs) are in a burgeoning area of materials research. The blend of high porosity, modifiability, and surface area of MOFs integrated with catalytically active nanoparticles offers unique functionality and versatility. This short review offers a concise overview associated with NP@MOFs. Introduction to NP@MOFs include comment and exemplification of two categories of synthetic strategies, i.e.,"ship-in-a-bottle" strategy and "bottle-around-the-ship" strategy. Applications correlated to photocatalytic hydrogen generation, hydrogen gas storage, as well as lithium-ion battery electrodes have also been reviewed. At last, the current challenges and opportunities involving synthesis protocols and energy related applications are given. (C) 2017 Elsevier Ltd. All rights reserved.
引用
收藏
页码:385 / 394
页数:10
相关论文
共 96 条
[1]   Catalysis with Metal Nanoparticles Immobilized within the Pores of Metal-Organic Frameworks [J].
Aijaz, Arshad ;
Xu, Qiang .
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2014, 5 (08) :1400-1411
[2]   Confinement of Ultrasmall Cu/ZnOx Nanoparticles in Metal-Organic Frameworks for Selective Methanol Synthesis from Catalytic Hydrogenation of CO2 [J].
An, Bing ;
Zhang, Jingzheng ;
Cheng, Kang ;
Ji, Pengfei ;
Wang, Cheng ;
Lin, Wenbin .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (10) :3834-3840
[3]   Toxic gas removal - metal-organic frameworks for the capture and degradation of toxic gases and vapours [J].
Barea, Elisa ;
Montoro, Carmen ;
Navarro, Jorge A. R. .
CHEMICAL SOCIETY REVIEWS, 2014, 43 (16) :5419-5430
[4]   Terminology of metal-organic frameworks and coordination polymers (IUPAC Recommendations 2013) [J].
Batten, Stuart R. ;
Champness, Neil R. ;
Chen, Xiao-Ming ;
Garcia-Martinez, Javier ;
Kitagawa, Susumu ;
Ohrstrom, Lars ;
O'Keeffe, Michael ;
Suh, Myunghyun Paik ;
Reedijk, Jan .
PURE AND APPLIED CHEMISTRY, 2013, 85 (08) :1715-1724
[5]   ADLINEATION PORTHOLES SPILLOVER [J].
BOUDART, M ;
VANNICE, MA ;
BENSON, JE .
ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-FRANKFURT, 1969, 64 (1-4) :171-&
[6]   Chromium(III) Terephthalate Metal Organic Framework (MIL-101): HF-Free Synthesis, Structure, Polyoxometalate Composites, and Catalytic Properties [J].
Bromberg, Lev ;
Diao, Ying ;
Wu, Huimeng ;
Speakman, Scott A. ;
Hatton, T. Alan .
CHEMISTRY OF MATERIALS, 2012, 24 (09) :1664-1675
[7]   A Robust Metal-Organic Framework Combining Open Metal Sites and Polar Groups for Methane Purification and CO2/Fluorocarbon Capture [J].
Chen, Cheng-Xia ;
Zheng, Shao-Ping ;
Wei, Zhang-Wen ;
Cao, Chen-Chen ;
Wang, Hai-Ping ;
Wang, Dawei ;
Jiang, Ji-Jun ;
Fenske, Dieter ;
Su, Cheng-Yong .
CHEMISTRY-A EUROPEAN JOURNAL, 2017, 23 (17) :4060-4064
[8]   One-pot synthesis of Pd@MOF composites without the addition of stabilizing agents [J].
Chen, Liyu ;
Chen, Huirong ;
Li, Yingwei .
CHEMICAL COMMUNICATIONS, 2014, 50 (94) :14752-14755
[9]   Metal-organic framework encapsulated Pd nanoparticles: towards advanced heterogeneous catalysts [J].
Chen, Liyu ;
Chen, Huirong ;
Luque, Rafael ;
Li, Yingwei .
CHEMICAL SCIENCE, 2014, 5 (10) :3708-3714
[10]   Multifunctional PdAg@MIL-101 for One-Pot Cascade Reactions: Combination of Host-Guest Cooperation and Bimetallic Synergy in Catalysis [J].
Chen, Yu-Zhen ;
Zhou, Yu-Xiao ;
Wang, Hengwei ;
Lu, Junling ;
Uchida, Takeyuki ;
Qiang, Xu ;
Yu, Shu-Hong ;
Jiang, Hai-Long .
ACS CATALYSIS, 2015, 5 (04) :2062-2069