Aluminum alkyl-mediated route to novel N,N,O-chelates for five-coordinate iron(II) chloride complexes:: Synthesis, structures, and ethylene polymerization studies

被引：51

作者：

Gibson, Vernon C.

Redshaw, Carl ^{[1
]}

Solan, Gregory A.

White, Andrew J. P.

Williarns, David J.

机构：

[1] Univ E Anglia, Sch Chem Sci & Pharm, Wolfson Mat & Catalysis Ctr, Norwich NR4 7TJ, Norfolk, England

[2] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England

[3] Univ Leicester, Dept Chem, Leicester LE1 7RH, Leics, England

来源：

ORGANOMETALLICS | 2007年 / 26卷 / 20期

关键词：

D O I：

10.1021/om700611q

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two five-coordinate iron(II) chloride complexes bearing 2-imine-6-(methyl alcohol)pyridine chelates have been prepared via an aluminum-mediated methyl migration route from the corresponding 2-acetyl-6-iminopyridine. Both iron complexes display moderate activity for ethylene polymerization on treatment with excess methylaluminoxane, affording highly linear polymers along with some oligomeric products.

引用

页码：5119 / 5123

页数：5

共 14 条

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