Ruthenium-Based Complexes Bearing Quaternary Ammonium Tags as Versatile Catalysts for Olefin Metathesis: From the Discovery to Practical Applications

被引：20

作者：

Olszewski, Tomasz K. ^{[1
]}

Bieniek, Michal ^{[2
]}

Skowerski, Krzysztof ^{[2
]}

机构：

[1] Wroclaw Univ Sci & Technol, Fac Chem, PL-50370 Wroclaw, Poland

[2] Apeiron Synth SA, PL-54427 Wroclaw, Poland

来源：

ORGANIC PROCESS RESEARCH & DEVELOPMENT | 2020年 / 24卷 / 02期

关键词：

olefin metathesis; heterogeneous catalysts; ruthenium contamination; ammonium tag; ruthenium; RING-CLOSING METATHESIS; CASHEW NUT SHELL; LARGE-SCALE SYNTHESIS; CROSS-METATHESIS; HETEROGENEOUS CATALYSTS; HIGHLY EFFICIENT; METAL-COMPLEXES; NHC LIGAND; SILICA; POLYMERIZATION;

D O I：

10.1021/acs.oprd.9b00483

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

This personal account describes the development and fine-tuning of pH-neutral quaternary-ammonium-tagged ruthenium-based complexes, their use as versatile catalysts for olefin metathesis, and the application of that transformation in the synthesis of complex molecules.

引用

页码：125 / 145

页数：21

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