Synthesis and structural characterization of the first mixed lanthanacarborane incorporating η5-cyclopentadienyl and η6-carboranyl ligands

被引：46

作者：

Xie, ZW ^{[1
]}

Wang, SW ^{[1
]}

Zhou, ZY ^{[1
]}

Mak, TCW ^{[1
]}

机构：

[1] Chinese Univ Hong Kong, Dept Chem, Shatin, NT, Hong Kong

来源：

ORGANOMETALLICS | 1998年 / 17卷 / 10期

关键词：

D O I：

10.1021/om971131k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of SmI2(THF)(x) with 2 equiv of [Me2Si(C2B10H11)(C5H4)]Na in THF, followed by extraction with toluene, gave [Me2Si(C2B10H11(C5H4)]Sm-(THF)(2) II), which represents the first structurally characterized example of the mixed lanthanacarborane incorporating eta(5)-cyclopentadienyl and eta(6)-carboranyl ligands. Unlike the SmI2 case, interaction of YbI2(THF)(x) with 2 equiv of [Me2Si(C2B10H11)(C5H4)]Na in THF afforded [Me2Si(C2B10H11)(C5H4)](2)Yb(THF)(2) (2).

引用

页码：1907 / 1909

页数：3

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