Liquid Crystalline Esters of Dibenzophenazines

被引：7

作者：

Bozek, Kevin John Anthony ^{[1
]}

Ho, Kuan I. ^{[1
]}

Saint-Martin, Tom ^{[1
,2
]}

Argyropoulos, Panos ^{[1
]}

Williams, Vance E. ^{[1
]}

机构：

[1] Simon Fraser Univ, Dept Chem, Burnaby, BC V5A 1S6, Canada

[2] Univ Paris 06, Dept Chem, F-75252 Paris, France

来源：

MATERIALS | 2015年 / 8卷 / 01期

基金：

加拿大自然科学与工程研究理事会;

关键词：

dibenzophenazine; discotic; columnar liquid crystal; THERMAL PHASE-BEHAVIOR; DISK-LIKE MOLECULES; CHAINS; OLIGOMERS; MESOGENS; DIMERS;

D O I：

10.3390/ma8010270

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A series of esters of 2,3,6,7-tetrakis(hexyloxy)dibenzo[a,c]phenazine-11-carboxylic acid was prepared in order to probe the effects of the ester groups on the liquid crystalline behavior. These compounds exhibit columnar hexagonal phases over broad temperature ranges. Variations in chain length, branching, terminal groups, and the presence of cyclic groups were found to modify transition temperatures without substantially destabilizing the mesophase range.

引用

页码：270 / 284

页数：15

共 30 条

[1] Fluorescent columnar liquid crystalline 3,4,9,10-tetra-(n-alkoxycarbonyl)-perylenes [J].

Benning, S ;

Kitzerow, HS ;

Bock, H ;

Achard, MF .

LIQUID CRYSTALS, 2000, 27 (07) :901-906

[2]

Benning SA, 2001, LIQ CRYST, V28, P1105, DOI 10.1080/02678290110048732

[3] A rational synthesis of polyacrylates with discogenic side groups [J].

Boden, N ;

Bushby, RJ ;

Lu, ZB .

LIQUID CRYSTALS, 1998, 25 (01) :47-58

[4] Folded discotic dimers [J].

Bozek, Kevin J. A. ;

Williams, Vance E. .

SOFT MATTER, 2014, 10 (31) :5749-5754

[5] Liquid crystals that affected the world: discotic liquid crystals [J].

Bushby, Richard J. ;

Kawata, Ken .

LIQUID CRYSTALS, 2011, 38 (11-12) :1415-1426

[6] CONTROL OF THERMAL PHASE-BEHAVIOR OF DISK-LIKE MOLECULES BY MODIFICATION OF SIDE-CHAIN STRUCTURE [J].

COLLARD, DM ;

LILLYA, CP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (05) :1829-1830

[7] STRUCTURE PROPERTY RELATIONSHIPS FOR THE THERMAL PHASE-BEHAVIOR OF DISCOTIC LIQUID-CRYSTALS - THE EFFECT OF BRANCHING AND UNSATURATION IN THE SIDE-CHAINS OF DISK-LIKE MOLECULES [J].

COLLARD, DM ;

LILLYA, CP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (23) :8577-8583

[8] Structural factors controlling the self-assembly of columnar liquid crystals [J].

Foster, E. Johan ;

Jones, R. Bradley ;

Lavigueur, Christine ;

Williams, Vance E. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (26) :8569-8574

[9] Self-assembly of hydrogen-bonded molecules: discotic and elliptical mesogens [J].

Foster, EJ ;

Lavigueur, C ;

Ke, YC ;

Williams, VE .

JOURNAL OF MATERIALS CHEMISTRY, 2005, 15 (37) :4062-4068

[10] Star-shaped discotic oligomesogens based on radial pentakisphenylethynylbenzene moieties [J].

Grafe, A ;

Janietz, D ;

Frese, T ;

Wendorff, JH .

CHEMISTRY OF MATERIALS, 2005, 17 (20) :4979-4984

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