Rational controlled morphological transitions in the self-assembled multi-headed giant surfactants in solution

被引：34

作者：

Chu, Yang ^{[1
]}

Zhang, Wei ^{[1
]}

Lu, Xinlin ^{[1
]}

Mu, Gaoyan ^{[1
]}

Zhang, Baofang ^{[1
]}

Li, Yiwen ^{[2
]}

Cheng, Stephen Z. D. ^{[1
]}

Liu, Tianbo ^{[1
]}

机构：

[1] Univ Akron, Dept Polymer Engn, Akron, OH 44325 USA

[2] Sichuan Univ, Coll Polymer Sci & Engn, State Key Lab Polymer Mat Engn, Chengdu 610065, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 56期

基金：

美国国家科学基金会;

关键词：

BLOCK-COPOLYMERS; MOLECULAR NANOPARTICLES; HIGHLY EFFICIENT; BUILDING-BLOCKS; VESICLES; DESULFURIZATION; CONSTRUCTION; CATALYSTS; SCIENCE; ACID);

D O I：

10.1039/c6cc04567g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of multi-headed giant surfactants based on polystyrene (PS)-polyhedral oligomeric silsesquioxane(s) (POSS) conjugates, with a different number and topology of POSS heads, are found to self-assemble into different supramolecular structures including vesicles, cylindrical and spherical micelles in H2O/DMF mixed solvents. The transitions among different morphologies can be rationally controlled by tuning the number and topology of POSS heads, as well as the macromolecular concentration.

引用

页码：8687 / 8690

页数：4

共 5 条

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