High-Density Energetic Mono- or Bis(Oxy)-5-Nitroiminotetrazoles

被引：181

作者：

Joo, Young-Hyuk ^{[1
]}

Shreeve, Jean'ne M. ^{[1
]}

机构：

[1] Univ Idaho, Dept Chem, Moscow, ID 83844 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 40期

关键词：

detonation properties; energetic materials; tetrazole; NITROGEN-RICH SALTS; DERIVATIVES;

D O I：

10.1002/anie.201003866

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Making an impact: Oxy-5-aminotetrazoles, which were obtained from the reaction of cyanogen azide and alkyl oxy-amine in 100% nitric acid (see scheme), give a series of highly energetic oxy-5-nitroiminotetrazolates in good yield. These compounds exhibit good physical and detonation properties, such as moderate thermal stabilities, high densities, high endothermy, good detonation pressures P, and good detonation velocities D. © 2010 Wiley-VCH Verlag GmbH and Co. KGaA, Weinheim.

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收藏

页码：7320 / 7323

页数：4

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