trans-dichloro[(1RS,4RS,5SR,7RS,8SR,11SR,12RS,14SR)-5,7,12,14-tetramethyl-1,4,8,11-tetraazacyclotetradecane-κ4N]cobalt(III) perchlorate

被引：1

作者：

Panneerselvam, K ^{[1
]}

Lu, TH

Tung, SF

Liu, GS

Chi, TY

Chung, CS

机构：

[1] Natl Tsing Hua Univ, Dept Phys, Hsinchu 300, Taiwan

[2] Natl Cheng Kung Univ, So Instrument Ctr, Tainan 701, Taiwan

[3] Natl Tsing Hua Univ, Dept Chem, Hsinchu 300, Taiwan

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1998年 / 54卷

关键词：

D O I：

10.1107/S0108270197019690

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal and molecular structure of the title compound, [CoCl2(C14H32N4)]ClO4, has been determined. The Co-III ion is six-coordinate with a distorted octahedral geometry consisting of the four N atoms of the macrocyclic ligand in equatorial positions and the two Cl atoms in axial positions. The tetradentate macrocyclic ligand adopts its most stable configuration, with two six-membered rings in chair conformations and two five-membered rings in gauche forms.

引用

页码：714 / 716

页数：3

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