Studies on monoxide emission spectrometry of rare earth elements - Part V. Determination of Dy in rare earth concentrates by dual wavelength method

被引:6
作者
Chen, Y
Zhang, J [1 ]
Zhang, ZH
Chen, JH
机构
[1] Fuzhou Univ, Cent Labs, Fujian 350002, Peoples R China
[2] Fuzhou Univ, Dept Chem, Fujian 350002, Peoples R China
关键词
dysprosium; praseodymium; enhancement effect; monoxide flame emission spectrometry; dual wavelength method;
D O I
10.1039/a708895g
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The enhancement effect of Pr, Y, Eu and La on the determination of Dy by air-acetylene flame monoxide flame emission spectrometry is reported. The dual wavelength method (526.3 nm as the analytical wavelength and 526.7 nm as the reference wavelength) was used to eliminate spectral interferences. A new method was established for direct determination of Dy (about 4%) in rare-earth mixture concentrates using Pr as enhancing agent and chemical interference inhibitor. The detection limit is 0.4 mu g ml(-1) Dy and the linear range is; 5-900 mu g ml(-1) Dy.
引用
收藏
页码:1235 / 1237
页数:3
相关论文
共 6 条
[1]   ATOMIC-EMISSION SPECTROSCOPY OF RARE EARTH ELEMENTS IN A SEPARATED NITROUS OXIDE-ACETYLENE FLAME [J].
HINGLE, DN ;
KIRKBRIG.GF ;
WEST, TS .
ANALYST, 1969, 94 (1123) :864-&
[2]   Studies on monoxide flame emission spectrometry of rare-earth elements .2. Determination of yttrium in rare-earth concentrates by the dual wavelength method [J].
Jie, Z ;
Zhang, ZZ ;
Ying, C ;
Chen, HZ .
ANALYTICA CHIMICA ACTA, 1997, 344 (03) :291-296
[3]  
OTRUBE V, 1989, FRESEN Z ANAL CHEM, V335, P890
[4]  
ZHANG J, 1998, CHIN ANAL LAB, V17, P24
[5]   Studies on monoxide emission spectrometry of rare-earth elements .4. Simultaneous determination of Sm, Eu, Gd in Sm-Eu-Gd concentrates by the dual wavelength method [J].
Zhang, ZZ ;
Zhang, J ;
Chen, Y ;
Tu, CH ;
Zheng, JD .
ANALYTICA CHIMICA ACTA, 1997, 350 (03) :365-369
[6]  
ZHANG ZZ, 1997, J CHIN RARE EARTH, V15, P86