The Synthesis of (2S, 3S, 4R)-2,3-Dialkyl-N-Phenyl-1,2,3,4-Tetrahydro-4-Quinolinamines in the Presence of Crystalline and Amorphous Aluminosilicates

被引：5
|
作者：
Grigor'eva, N. G. [1 ,2 ]
Kostyleva, S. A. [1 ]
Artem'eva, A. S. [2 ]
Bubennov, S. V. [1 ]
Kutepov, B. I. [1 ,2 ]
机构：
[1] Russian Acad Sci, Inst Petr Chem & Catalysis, Ufa 450075, Bashkortostan, Russia
[2] Ufa State Petr Technol Univ, Ufa 450062, Bashkortostan, Russia
来源：
PETROLEUM CHEMISTRY | 2020年 / 60卷 / 04期
基金：
俄罗斯科学基金会;
关键词：
(2S; 3S; 4R)-2; 3-dialkyl-N-phenyl-1; 2; 3; 4-tetrahydro-4-quinolinamines; aniline; aldehydes; cyclocondensation; zeolites; hierarchical zeolites; mesoporous aluminosilicates; DIELS-ALDER REACTION; SOL-GEL SYNTHESIS; ENANTIOSELECTIVE SYNTHESIS; POVAROV REACTION; ACID; DERIVATIVES; ALDEHYDES; TETRAHYDROQUINOLINES; REARRANGEMENT; CONVERSION;
D O I：
10.1134/S0965544120040088
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The catalytic activity of micro- and micro-meso-macroporous zeolites of the FAU structural type and an ASM mesoporous aluminosilicate in the reaction of aniline with C-3-C-5 aldehydes has been studied. It has been established that under the studied conditions, (2S, 3S, 4R)-2,3-dialkyl-N-phenyl-1,2,3,4-tetrahydro-4-quinolinamines are the main products formed over the tested catalysts with the selectivity of up to 71%.
引用
收藏
页码：525 / 531
页数：7
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