Iron-Catalyzed Asymmetric Hydrosilylation of 1,1-Disubstituted Alkenes

被引：144

作者：

Chen, Jianhui ^{[1
]}

Cheng, Biao ^{[1
]}

Cao, Minyi ^{[1
]}

Lu, Zhan ^{[1
]}

机构：

[1] Zhejiang Univ, Dept Chem, Hangzhou 310028, Zhejiang, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2015年 / 54卷 / 15期

基金：

美国国家科学基金会;

关键词：

arenes; asymmetric catalysis; iron; silicon; synthetic methods; ORGANIC-SYNTHESIS; ARYL ALKENES; ENANTIOSELECTIVE HYDROSILYLATION; FUNCTIONALIZED HYDROXYLAMINES; INTRAMOLECULAR HYDROSILATION; PHOSPHORAMIDITE LIGANDS; THYMOL DERIVATIVES; ABSOLUTE HELICITY; OLEFINS; HYDROGENATION;

D O I：

10.1002/anie.201411884

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The highly regio- and enantioselective iron-catalyzed anti-Markovnikov hydrosilylation of 1,1-disubstituted aryl alkenes was developed using iminopyridine oxazoline ligands to afford chiral organosilanes. Additional derivatization of these products lead to chiral organosilanols, cyclic silanes, phenol derivatives, and 3-substituted 2,3-dihydrobenzofurans.

引用

页码：4661 / 4664

页数：4

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