Synchrotron based FTIR spectromicroscopy of biopolymer blends undergoing phase separation

被引:18
作者
De Giacomo, O. [1 ]
Cesaro, A. [1 ]
Quaroni, L. [2 ,3 ]
机构
[1] Univ Trieste, Dept Biochem Biophys & Macromol Chem, I-34127 Trieste, Italy
[2] Univ Saskatchewan, Canadian Light Source Inc, Mid IR Beamline, Saskatoon, SK S7N 0X4, Canada
[3] Elettra Sincrotrone Trieste, I-34012 Trieste, Italy
关键词
synchrotron; FTIR spectromicroscopy; phase separation; biopolymers; microtexture;
D O I
10.1007/s11483-007-9051-6
中图分类号
TS2 [食品工业];
学科分类号
0832 ;
摘要
The results of a FTIR microspectroscopy analysis performed on the mixed gelling system of a protein (gelatin) and a polysaccharide (maltodextrin) are presented. A series of spectra were acquired consecutively by raster scanning the surface over a region of interest. The analysis has been carried out on three mixed-biopolymer samples prepared following different temperature paths, to study the effects of kinetics and thermodynamics on the texture of the final product. The chemical mapping has revealed to be very sensitive to composition, physical structure and hydration of the biopolymers. The results are critically discussed in reference to the band assignments and to protocols of sample preparation on the microtexture of the thin film.
引用
收藏
页码:77 / 86
页数:10
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