Glassy dynamics of gelatin gels

被引:28
作者
Parker, Alan [1 ]
Normand, Valery [1 ]
机构
[1] Firmenich Co, Corp Res Div, CH-1217 Geneva, Switzerland
关键词
SPIN-GLASSES; POLYMER GLASS; MASTER CURVE; MEMORY; TEMPERATURE; SYSTEMS; ELASTICITY; COLLAGEN; HELIX;
D O I
10.1039/c0sm00472c
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We measure the elasticity of thermoreversible gelatin gels during slow cool and heat cycles, with and without stops. The responses are measures of the system energy, since elasticity is a function of the helix fraction, which quantifies the system's order. They show the same memory and rejuvenation effects as magnetic spin glasses. At constant temperature, all gels reach an aging regime, where their responses decrease linearly in log(time), like many other glassy systems. Complex memory effects occur after temperature jumps. We suggest that the parallels between gelatin gels and other glassy systems are due to their temperature-dependent, rugged, hierarchical energy landscapes. Gelatin gels act rather like "colloidal spin glasses''. However, unlike magnetic spin glasses, their size and time scales should allow experimental measurement of the relation between mesoscopic dynamics and macroscopic behaviour.
引用
收藏
页码:4916 / 4919
页数:4
相关论文
共 38 条
[1]   Evolution in complex systems [J].
Anderson, PE ;
Jensen, HJ ;
Oliveira, LP ;
Sibani, P .
COMPLEXITY, 2004, 10 (01) :49-56
[2]   FOLDING MECHANISM OF THE TRIPLE HELIX IN TYPE-III COLAGEN AND TYPE-III PN-COLLAGEN - ROLE OF DISULFIDE BRIDGES AND PEPTIDE-BOND ISOMERIZATION [J].
BACHINGER, HP ;
BRUCKNER, P ;
TIMPL, R ;
PROCKOP, DJ ;
ENGEL, J .
EUROPEAN JOURNAL OF BIOCHEMISTRY, 1980, 106 (02) :619-632
[3]   Advanced memory effects in the aging of a polymer glass [J].
Bellon, L ;
Ciliberto, S ;
Laroche, C .
EUROPEAN PHYSICAL JOURNAL B, 2002, 25 (02) :223-231
[4]   Memory in the aging of a polymer glass [J].
Bellon, L ;
Ciliberto, S ;
Laroche, C .
EUROPHYSICS LETTERS, 2000, 51 (05) :551-556
[5]  
Bouchaud J.P., 2000, SOFT FRAGILE MATTER
[6]  
BOUCHAUD J.-P., 1998, SPIN GLASSES RANDOM
[7]   Intermittent origin of the large violations of the fluctuation-dissipation relations in an aging polymer glass [J].
Buisson, L ;
Ciliberto, S ;
Garcimartín, A .
EUROPHYSICS LETTERS, 2003, 63 (04) :603-609
[8]  
CHATELLIER JY, 1985, INT J BIOL MACROMOL, V7, P311, DOI 10.1016/0141-8130(85)90030-3
[9]  
De Gennes P.-G, 1979, Scaling concepts in polymer physics
[10]   Time-resolved-correlation measurements of temporally heterogeneous dynamics [J].
Duri, A ;
Bissig, H ;
Trappe, V ;
Cipelletti, L .
PHYSICAL REVIEW E, 2005, 72 (05)