trans-Bis(2,2-diphenylethylaminexN)bis(5,5-diphenylhydantoinato- κN3)copper(II) and its chloroform disolvate

被引：18

作者：

Akitsu, T ^{[1
]}

Einaga, Y ^{[1
]}

机构：

[1] Keio Univ, Fac Sci & Technol, Dept Chem, Kohoku Ku, Yokohama, Kanagawa 2238522, Japan

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2005年 / 61卷

关键词：

D O I：

10.1107/S010827010500209X

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal structures of the title compounds, [Cu(C15H11N2O2)(2)(C14H15N)(2)] and [Cu(C15H11N2O2)(2)(C14H15N)(2)]center dot 2CHCl(3), respectively, have been determined. The red disolvate complex affords a square-planar CuN4 coordination environment in which the Cu-II atom lies on a centre of symmetry. The blue solvent-free complex affords a distorted square-pyramidal CuN4O coordination environment and adjacent molecules form centrosymmetric dimers. A comparison of the different crystal structures focuses on the role of the solvent molecules in supramolecular assemblies of the copper(II) complexes.

引用

页码：M183 / M186

页数：4

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