Synthesis, Crystal Structure and Thermal Stability of 1D Manganese Coordination Polymer [Mn(1,5-nds)(Him)4]n

被引：0

作者：

Qian Bao-Hua ^{[2
]}

Ma Wei-Xing ^{[2
]}

Lu Lu-De ^{[1
]}

Yang Xu-Jie ^{[1
]}

Wang Xin ^{[1
]}

机构：

[1] Nanjing Univ Sci & Technol, Mat Chem Lab, Nanjing 210094, Peoples R China

[2] Huaihai Inst Technol, Sch Chem Technol, Lianyungang 222005, Jiangsu, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2010年 / 26卷 / 07期

关键词：

manganese(II) complex; coordination polymer; 1,5-naphthalenedisulfonate; crystal structure; thermal stability; CHEMISTRY; LIGAND; ARENEDISULFONATES; COBALT(II); FRAMEWORKS; DESIGN; CUBANE; MODE;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis, structural characterization and thermal behavior of a novel one-dimensional manganese (II) complex of formula [Mn(1,5-nds)(Him)(4)](n) [1,5-nds=naphthalene-1,5-disulfonate, Him=imidazole] is reported. The complex crystallizes in the triclinic system, space group P (1) over bar, with a=0.835 42(13) nm, b=0.983 45(18) nm, c=0.987 42(19) nm, alpha=60.523 0(10)degrees, beta=97.748(2)degrees, gamma=87.189(2)degrees and Z=2. The 1,5-nds ligand assumes the mu(2) coordination mode and interlinks Mn(II) ions into infinite one-dimensional chain structure along [11 (1) over bar] direction, with the adjacent Mn center dot center dot center dot Mn distance being 1.144 99(12) nm. The chains are assembled into a three-dimensional supramolecular architecture via hydrogen bonds and C-H center dot center dot center dot pi interactions. IR spectra and thermal analysis data are in agreement with the crystal structure. CCDC: 773063.

引用

页码：1289 / 1293

页数：5

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