Diaquabis(4,4′-bipyridine-κN)bis(2,4,5-trifluoro-3-hydroxybenzoato-κO1)manganese(II)

被引:0
作者
Min, Chun-Gang [1 ]
Yang, Xi-Kun [1 ]
机构
[1] Kunming Univ Sci & Technol, Res Ctr Anal & Measurement, Kunming 650093, Yunnan, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
基金
中国国家自然科学基金;
关键词
data-to-parameter ratio = 11.6; mean σ(C-C) = 0.004 Å; R factor = 0.038; single-crystal X-ray study; T = 298 K; wR factor = 0.084;
D O I
10.1107/S1600536811049610
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, [Mn(C7H2F3O3)(2)(C10H8N2)(2)(H2O)(2)], the Mn-II ion, situated on a centre of inversion, has a distorted octahedral coordination geometry and is coordinated by two N atoms from two 4,4'-bipyridine ligands, two O atoms from two 2,4,5-trifluoro-3-hydroxybenzoate ligands and two water molecules. Intermolecular O-H center dot center dot center dot N hydrogen bonds link the molecules into a chain along the a axis. Interactions between neighboring chains occur through O-H center dot center dot center dot O hydrogen bonds, which link the chains into a two-dimensional supramolecular network parallel to the ac plane. In addition, O-H center dot center dot center dot O hydrogen bonds between the water molecules and carboxylate groups also exist in the the crystal structure.
引用
收藏
页码:M1826 / U463
页数:11
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