A straightforward and versatile protocol for the direct conversion of benzylic azides to ketones and aldehydes

被引：4

作者：

Gonzalez-Calderon, Davir ^{[1
]}

Morales-Reza, Marco A. ^{[1
]}

Diaz-Torres, Eduardo ^{[1
]}

Fuentes-Benites, Aydee ^{[1
]}

Gonzalez-Romero, Carlos ^{[1
]}

机构：

[1] Univ Autonoma Estado Mexico, Fac Quim, Dept Quim Organ, Paseo Colon Paseo Tollocan S-N, Toluca 50120, Estado De Mexic, Mexico

来源：

RSC ADVANCES | 2016年 / 6卷 / 87期

关键词：

ORGANIC AZIDES; VINYL AZIDES; INORGANIC PERSPECTIVE; ALKYNE CYCLOADDITION; SCHMIDT REACTION; FACILE SYNTHESIS; CLICK-CHEMISTRY; METAL AZIDES; ONE-POT; OXIDATION;

D O I：

10.1039/c6ra13088g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of carbonyl compounds from benzylic azides through benzylideneamides is described for the first time. NaH-mediated activation of benzyl azides allows a rapid water-promoted oxidation under a facile protocol with good yields.

引用

页码：83547 / 83550

页数：4

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