A straightforward and versatile protocol for the direct conversion of benzylic azides to ketones and aldehydes

被引：4
|
作者：
Gonzalez-Calderon, Davir [1 ]
Morales-Reza, Marco A. [1 ]
Diaz-Torres, Eduardo [1 ]
Fuentes-Benites, Aydee [1 ]
Gonzalez-Romero, Carlos [1 ]
机构：
[1] Univ Autonoma Estado Mexico, Fac Quim, Dept Quim Organ, Paseo Colon Paseo Tollocan S-N, Toluca 50120, Estado De Mexic, Mexico
来源：
RSC ADVANCES | 2016年 / 6卷 / 87期
关键词：
ORGANIC AZIDES; VINYL AZIDES; INORGANIC PERSPECTIVE; ALKYNE CYCLOADDITION; SCHMIDT REACTION; FACILE SYNTHESIS; CLICK-CHEMISTRY; METAL AZIDES; ONE-POT; OXIDATION;
D O I：
10.1039/c6ra13088g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The synthesis of carbonyl compounds from benzylic azides through benzylideneamides is described for the first time. NaH-mediated activation of benzyl azides allows a rapid water-promoted oxidation under a facile protocol with good yields.
引用
收藏
页码：83547 / 83550
页数：4
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