Sawhorse connections in a Ag(I)-nitrite coordination network:: {[Ag(pyrazine)]NO2}∞

被引：57
作者：
Blake, AJ
Champness, NR
Crew, M
Parsons, S
机构：
[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England
[2] Univ Edinburgh, Dept Chem, Edinburgh EH9 3JJ, Midlothian, Scotland
来源：
NEW JOURNAL OF CHEMISTRY | 1999年 / 23卷 / 01期
关键词：
D O I：
10.1039/a808025i
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The Ag(8) coordination networks, {[Ag(pyrazine)]NO2}(infinity) and {[Ag(4,4'-bipy)]NO2}(infinity) have been constructed in order to investigate the effect of anion upon network topology; an unusual sawhorse connection is observed in the structure of {[Ag(pyrazine)]NO2}(infinity) with the nitrite anion acting to 'block' cis coordination sites.
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页码：13 / 15
页数：3
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