In situ poly(ethylene terephthalate) microfibers- and shear-induced non-isothermal crystallization of isotactic polypropylene by on-line small angle X-ray scattering

In situ microfibrillar reinforced blend (MRB) based on poly(ethylene terephthalate) (PET) and isotactic polypropylene (iPP) was elaborated by a slit die extrusion, hot stretching, and quenching process. The scanning electronic microscopic images show well-developed PET microfibers in the blends. The on-line small angle X-ray scattering (SAXS) test shows that PET microfibers have high nucleation for iPP crystallization. At the same time, after shear, neat iPP and microfibrillar blend both can faster crystallization rate. Three nucleation origins are proposed in microfibrillar reinforced blends under shear flow field: (a) the classical row nuclei model, (b) fiber nuclei and (c) nuclei induced by fiber assistant alignment. The polarized optical microscopic images indicate that, during the non-isothermal crystallization at a cooling rate of 10 degrees C/min from 200 degrees C to room temperature, the neat iPP forms common spherulites, while the diluted microfibrillar blend with 1 wt% of PET has a typical transcrystalline structure. (c) 2005 Elsevier Ltd. All rights reserved.