Self-assembled carbon nitride/cobalt (III) porphyrin photocatalyst for mimicking natural photosynthesis

被引：39

作者：

Singh, Chandani ^{[1
]}

Chaubey, Surabhi ^{[1
]}

Singh, Pooja ^{[1
]}

Sharma, Kavita ^{[1
]}

Shambhavi ^{[1
]}

Kumar, Abhishek ^{[2
]}

Yadav, Rajesh K. ^{[1
]}

Dwivedi, D. K. ^{[5
]}

Baeg, Jin-Ook ^{[3
]}

Kumar, Utkarsh ^{[4
]}

Yadav, B. C. ^{[4
]}

Pandey, Gajanan ^{[4
]}

机构：

[1] Madan Mohan Malaviya Univ Technol, Dept Chem & Environm Sci, Gorakhpur 273010, UP, India

[2] Indian Inst Technol Delhi, Dept Chem, New Delhi 110016, India

[3] Korea Res Inst Technol, Artificial Photosynth Res Grp, 100 Jang Dong, Daejeon 305600, South Korea

[4] Babasaheb Bhimrao Ambedkar Univ, Dept Chem & Phys, Lucknow 226025, UP, India

[5] Madan Mohan Malaviya Univ Technol, Dept Phys & Mat Sci, Gorakhpur 273010, UP, India

来源：

关键词：

carbon nitride; catalytic processes morphology; 1,4-NADH regeneration; L-glutamate production; SOLAR-ENERGY; BIVO4; PHOTOANODES; NADH REGENERATION; HIGHLY EFFICIENT; WATER; HETEROJUNCTION; DEGRADATION; MORPHOLOGY; REDUCTION; G-C3N4;

D O I：

10.1016/j.diamond.2019.107648

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Natural photosynthesis is the primary route that supplies energy required for the endurance of all living things. The initial step in this process is the absorption of solar light by an organic-inorganic molecular organization called a light harvesting complex. This complicated natural solar energy conversion platform has inspired scientists to create artificial counter parts. As a means to achieve this, a self-assembled light harvesting carbon nitride/cobalt tetra-phenyl-porphyrin (CN/Co(III)TPP) material as a highly selective solar light active photocatalyst has been developed. The system exhibited excellent NADH regeneration (87.87%) and L-glutamate (94.30%) production under visible light irradiation. The current research endeavor highlights the development and application of a self-assembled CN/Co(III)TPP photocatalyst for the selective production of L-glutamate from a-ketoglutaratc.

引用

页数：6

共 50 条

[1] Photosynthetic energy conversion: natural and artificial
Barber, James
[J]. CHEMICAL SOCIETY REVIEWS, 2009, 38 (01) : 185 - 196
[2] CONCENTRATION QUENCHING IN CHLOROPHYLL
BEDDARD, GS
PORTER, G
[J]. NATURE, 1976, 260 (5549) : 366 - 367
[3] A metal-free composite photocatalyst of graphene quantum dots deposited on red phosphorus
Chan, Donald K. L.
Yu, Jimmy C.
Li, Yecheng
Hu, Zhuofeng
[J]. JOURNAL OF ENVIRONMENTAL SCIENCES, 2017, 60 : 91 - 97
[4] Visible light photoactivity enhancement via CuTCPP hybridized g-C3N4 nanocomposite
Chen, Daimei
Wang, Kewei
Hong, Wangzhi
Zong, Ruilong
Yao, Wenqing
Zhu, Yongfa
[J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2015, 166 : 366 - 373
[5] Solar Energy Supply and Storage for the Legacy and Non legacy Worlds
Cook, Timothy R.
Dogutan, Dilek K.
Reece, Steven Y.
Surendranath, Yogesh
Teets, Thomas S.
Nocera, Daniel G.
[J]. CHEMICAL REVIEWS, 2010, 110 (11) : 6474 - 6502
[6] Croce R, 2014, NAT CHEM BIOL, V10, P492, DOI [10.1038/nchembio.1555, 10.1038/NCHEMBIO.1555]
[7] Correlation between the Structure and Catalytic Activity of [Cp*Rh(Substituted Bipyridine)] Complexes for NADH Regeneration
Ganesan, Vinothkumar
Sivanesan, Dharmalingam
Yoon, Sungho
[J]. INORGANIC CHEMISTRY, 2017, 56 (03) : 1366 - 1374
[8] Hollmann F, 2001, ANGEW CHEM INT EDIT, V40, P169, DOI 10.1002/1521-3773(20010105)40:1<169::AID-ANIE169>3.0.CO
[9] 2-T
[10] The Water Oxidation Bottleneck in Artificial Photosynthesis: How Can We Get Through It? An Alternative Route Involving a Two-Electron Process
Inoue, Haruo
Shimada, Tetsuya
Kou, Youki
Nabetani, Yu
Masui, Dai
Takagi, Shinsuke
Tachibana, Hiroshi
[J]. CHEMSUSCHEM, 2011, 4 (02) : 173 - 179

← 1 2 3 4 5 →