Catalytic asymmetric diamination of conjugated dienes and triene

被引：214

作者：

Du, Haifeng ^{[1
]}

Yuan, Weicheng ^{[1
]}

Zhao, Baoguo ^{[1
]}

Shi, Yian ^{[1
]}

机构：

[1] Colorado State Univ, Dept Chem, Ft Collins, CO 80523 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2007年 / 129卷 / 38期

关键词：

D O I：

10.1021/ja074698t

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This paper describes a catalytic asymmetric diamination process using di-tert -butyldiaziridinone as nitrogen source with catalyst generated from Pd-2(dba)(3) and chiral phosphorus amidite ligand. A wide variety of conjugated dienes and triene can be effectively diaminated in good yields with high regio-, diastereo-, and enantioselectivities.

引用

页码：11688 / +

页数：3

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