Specific method for spectrophotometric determination of molybdenum in soil

被引：2

作者：

Aggarwal, SG ^{[1
]}

Patel, KS ^{[1
]}

机构：

[1] Pt Ravishankar Shukla Univ, SOS Chem, Raipur 492010, Madhya Pradesh, India

来源：

MIKROCHIMICA ACTA | 1998年 / 129卷 / 3-4期

关键词：

molybdenum; spectrophotometry; solvent-extraction; sodium borohydride; thiocyanate; surfactants; soil;

D O I：

10.1007/BF01244750

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A new, simple and specific spectrophotometric method for the determination of Mo in the soil extracts is described. Mo(VI) is reduced to Mo(V) with sodium borohydride and allowed to react with SCN- ions in the presence of cationic and neutral surfactants e.g. CPC and TX-100 in the acidic aqueous solution. The molar absorptivity of the complex in both the aqueous, and toluene solutions is (2.30) x 10(4) 1 mol(-1) cm(-1) at absorption maximum, 460 nm. The extraction-procedure preconcentrated Mo at least 3-folds, the detection limit is 125 ng Mo/g soil. The analytical variables of the method have been optimised and composition of the complex is proposed. None of the tested foreign ion interfered in the determination of Mo up to a large amount. An attempt for the removal of Fe-interference in the determination of Mo in soil extract has been described. The method has been found to be satisfactorily applicable for the determination of Mo in hot water leachates and acid digested soil solutions at lower ppm levels.

引用

页码：265 / 269

页数：5

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