Two-dimensional modeling of a polymer electrolyte membrane fuel cell with long flow channel. Part I. Model development

A two-dimensional single-phase model is developed for the steady-state and transient analysis of polymer electrolyte membrane fuel cells (PEMFC). Based on diluted and concentrated solution theories, viscous flow is introduced into a phenomenological multi-component modeling framework in the membrane. Characteristic variables related to the water uptake are discussed. A Butler-Volmer formulation of the current-overpotential relationship is developed based on an elementary mechanism of electrochemical oxygen reduction. Validated by using published V-I experiments, the model is then used to analyze the effects of operating conditions on current output and water management, especially net water transport coefficient along the channel. For a power PEMFC, the long-channel configuration is helpful for internal humidification and anode water removal, operating in counterflow mode with proper gas flow rate and humidity. In time domain, a typical transient process with closed anode is also investigated. (C) 2014 Elsevier B.V. All rights reserved.