Acetamide: a low-cost alternative to alkyl imidazolium chlorides for aluminium-ion batteries

被引：55

作者：

Canever, Nicolo ^{[1
]}

Bertrand, Nicolas ^{[2
]}

Nann, Thomas ^{[1
]}

机构：

[1] Victoria Univ Wellington, Sch Chem & Phys Sci, Wellington, New Zealand

[2] Ecole Natl Super Chim Clermont Ferrand, SIGMA Clermont, Aubiere, France

来源：

CHEMICAL COMMUNICATIONS | 2018年 / 54卷 / 83期

关键词：

NATURAL GRAPHITE CATHODE; ELECTRODEPOSITION; INTERCALATION; MECHANISM; LIQUIDS;

D O I：

10.1039/c8cc04468f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We propose a new electrolyte for rechargeable aluminium-ion batteries based on a room-temperature eutectic mixture of acetamide and aluminium chloride. When diluted with dichloromethane, the electrolyte shows similar cycling performance to the more traditional 1-ethyl-3-methylimidazolium chloride-based electrolytes for a fraction of the cost.

引用

页码：11725 / 11728

页数：4

共 20 条

[1] Aluminium electrodeposition under ambient conditions [J].

Abbott, Andrew P. ;

Harris, Robert C. ;

Hsieh, Yi-Ting ;

Ryder, Karl S. ;

Sun, I-Wen .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2014, 16 (28) :14675-14681

[2] Electrodeposition of aluminium and aluminium/platinum alloys from AlCl3/benzyltrimethylammonium chloride room temperature ionic liquids [J].

Abbott, AP ;

Eardley, CA ;

Farley, NRS ;

Griffith, GA ;

Pratt, A .

JOURNAL OF APPLIED ELECTROCHEMISTRY, 2001, 31 (12) :1345-1350

[3] Do all ionic liquids need organic cations? Characterisation of [AlCl2•nAmide]+ AlCl4- and comparison with imidazolium based systems [J].

Abood, Hadi M. A. ;

Abbott, Andrew P. ;

Ballantyne, Andrew D. ;

Ryder, Karl S. .

CHEMICAL COMMUNICATIONS, 2011, 47 (12) :3523-3525

[4]

Antonio Elia G., 2017, J MATER CHEM A, V5, P9682

[5] The staging mechanism of AlCl4 intercalation in a graphite electrode for an aluminium-ion battery [J].

Bhauriyal, Preeti ;

Mahata, Arup ;

Pathak, Biswarup .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2017, 19 (11) :7980-7989

[6] Amorphous Vanadium Oxide/Carbon Composite Positive Electrode for Rechargeable Aluminum Battery [J].

Chiku, Masanobu ;

Takeda, Hiroki ;

Matsumura, Shota ;

Higuchi, Eiji ;

Inoue, Hiroshi .

ACS APPLIED MATERIALS & INTERFACES, 2015, 7 (44) :24385-24389

[7] A Raman spectroscopic study of graphene cathodes in high-performance aluminum ion batteries [J].

Childress, Anthony S. ;

Parajuli, Prakash ;

Zhu, Jingyi ;

Podila, Ramakrishna ;

Rao, Apparao M. .

NANO ENERGY, 2017, 39 :69-76

[8] An AlCl3 based ionic liquid with a neutral substituted pyridine ligand for electrochemical deposition of aluminum [J].

Fang, Youxing ;

Yoshii, Kazuki ;

Jiang, Xueguang ;

Sun, Xiao-Guang ;

Tsuda, Tetsuya ;

Mehio, Nada ;

Dai, Sheng .

ELECTROCHIMICA ACTA, 2015, 160 :82-88

[9] Confirming reversible Al3+ storage mechanism through intercalation of Al3+ into V2O5 nanowires in a rechargeable aluminum battery [J].

Gu, Sichen ;

Wang, Huali ;

Wu, Chuan ;

Bai, Ying ;

Li, Hong ;

Wu, Feng .

ENERGY STORAGE MATERIALS, 2017, 6 :9-17

[10] Electrodeposition of aluminium from ionic liquids:: Part I -: electrodeposition and surface morphology of aluminium from aluminium chloride (AlCl3)-l-ethyl-3-methylimidazolium chloride ([EMIm]Cl) ionic liquids [J].

Jiang, T. ;

Brym, M. J. Chollier ;

Dube, G. ;

Lasia, A. ;

Brisard, G. M. .

SURFACE & COATINGS TECHNOLOGY, 2006, 201 (1-2) :1-9

← 1 2 →