Thermodynamic Aspects of Dimethoxymethane Conversion into Hydrogen-Rich Gas

被引：3

作者：

Badmaev, S. D. ^{[1
]}

Belyaev, V. D. ^{[1
,2
]}

Sobyanin, V. A. ^{[1
,2
]}

机构：

[1] Russian Acad Sci, Boreskov Inst Catalysis, Siberian Branch, Novosibirsk 630090, Russia

[2] Russian Acad Sci, Inst Solid State Chem & Mechanochem, Siberian Branch, Novosibirsk 630128, Russia

来源：

KINETICS AND CATALYSIS | 2022年 / 63卷 / 03期

基金：

俄罗斯科学基金会;

关键词：

dimethoxymethane; thermodynamic analysis; steam reforming; partial oxidation; hydrogen; fuel cells; STEAM; PERFORMANCE; OXIDATION; METHANOL;

D O I：

10.1134/S0023158422030016

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A thermodynamic analysis of the conversion of dimethoxymethane by steam reforming and partial oxidation into a hydrogen-rich gas for fuel cell feeding has been carried out. Calculations were carried out at a pressure of 1 atm, temperatures of 100-1000 degrees C, and the molar ratios O-2/DMM = 0.5-3.5 and H2O/DMM = 1-5. The effects of temperature and reaction mixture composition on the equilibrium reaction product distribution and carbon (graphite) formation boundaries have been studied. The calculated data are compared with the known experimental results.

引用

页码：330 / 337

页数：8

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