Regulated and unregulated emissions from a spark-ignition engine fuelled with low-blend ethanol-gasoline mixtures

The effects of ethanol addition to gasoline on the exhaust emissions (including regulated and unregulated emissions) and the conversion efficiencies of the three-way catalyst (TWC) were investigated in a three-cylinder spark-ignition (SI) gasoline engine. Three typical fuel blends - commercial 93# (Research Octane Number) gasoline (E0), E10, and E20 (with 0 per cent, 10 per cent, and 20 per cent ethanol in the blends by volume) - were used in the experiment. Unregulated emissions were measured by gas chromatography with a pulsed discharge helium ionization detector. Experimental results show that the regulated emissions of hydrocarbon, carbon monoxide, and nitrogen oxides decreased before and after the TWC with the increase of ethanol fraction in the fuel blends. However, the unregulated emissions of ethanol, acetaldehyde, and formaldehyde increased with the increase of ethanol fraction and decreased with increased engine speed and/or torque. Ethanol emission was not detected when fuelled with gasoline (E0). Ethanol emission was intensively influenced by the exhaust temperature and disappeared when the exhaust temperature was higher than 900 K for E10 and E20 operation. Acetaldehyde emission definitely comes from the oxidation of ethanol; the engine speed and load have opposite effects on acetaldehyde emission. Both ethanol and acetaldehyde can be converted effectively by the TWC. More formaldehyde was emitted at higher engine speed and lower load operating conditions.