A New Application of a Mesoporous Hybrid of Tungsten Oxide and Carbon as an Adsorbent for Elimination of Sr2+ and Co2+ from an Aquatic Environment

被引:23
作者
Wang, Yanan [1 ]
Thuiyan Huang [2 ]
Duan, Shengxia [1 ,2 ]
Liu, Xia [1 ]
Sun, Ju [1 ]
Hayat, Tasawar [4 ,5 ]
Alsaedi, Ahmed [4 ]
Li, Jiaxing [1 ,3 ,4 ]
机构
[1] Chinese Acad Sci, Inst Plasma Phys, CAS Key Lab Photovolta & Energy Conservat Mat, POB 1126, Hefei 230031, Anhui, Peoples R China
[2] Wuyi Univ, Sch Chem & Environm Engn, Jiangmen 529020, Peoples R China
[3] Collaborat Innovat Ctr Radiat Med Jiangsu Higher, Suzhou 215123, Peoples R China
[4] King Abdulaziz Univ, Fac Sci, NAAM Res Grp, Jeddah 21589, Saudi Arabia
[5] Quaid I Azam Univ, Dept Math, Islamabad 44000, Pakistan
来源
ACS SUSTAINABLE CHEMISTRY & ENGINEERING | 2018年 / 6卷 / 02期
基金
中国国家自然科学基金;
关键词
Tungsten oxide and carbon; Sr2+; Co2+; adsorption; GRAPHENE OXIDE; AQUEOUS-SOLUTION; WASTE-WATER; CRYSTALLINE FRAMEWORK; EFFICIENT ENRICHMENT; HIGH-PERFORMANCE; CO(II) REMOVAL; METAL-OXIDES; ORGANIC-DYE; ADSORPTION;
D O I
10.1021/acssuschemeng.7b03818
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The mesoporous tungsten oxide and carbon (WOx/C) nanowire network was successfully synthesized using an environmentally friendly solvothermal method. The as-prepared composite was applied as an adsorbent for metal ion elimination from wastewater via batch experiments. The adsorption results suggested that the adsorption interactions between WOx/C and Sr2+ and Co2+ were pH-dependent, while the effect of ionic strength toward sorption capacity depended on the solution acidity and adsorbates. The sorption process followed the Langmuir model with the maximum sorption capacity of Sr2+ and Co2+ onto WOx/C being 175.0 and 326.0 mg/g at 308 K, respectively. Thermodynamic parameters, namely, Delta S degrees, Delta H degrees, and Delta G degrees, indicated an endothermic, but spontaneous adsorption process. All the exhibited results demonstrated that the as-synthesized WOx/C nanowire network has the potential to be an effective adsorbent for heavy metal ion remediation from aqueous solutions.
引用
收藏
页码:2462 / 2473
页数:12
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