TiO2 promoted Co/SiO2 catalysts for Fischer-Tropsch synthesis

被引：47

作者：

Hinchiranan, Sukamon ^{[1
,2
]}

Zhang, Yi ^{[2
]}

Nagamori, Satoshi ^{[2
]}

Vitidsant, Tharapong ^{[1
]}

Tsubaki, Noritatsu ^{[2
]}

机构：

[1] Chulalongkorn Univ, Fac Sci, Dept Chem Technol, Bangkok 10330, Thailand

[2] Toyama Univ, Sch Engn, Dept Appl Chem, Toyama 9308555, Japan

来源：

FUEL PROCESSING TECHNOLOGY | 2008年 / 89卷 / 04期

关键词：

Fischer-Tropsch synthesis; cobalt catalyst; titania; silica; syngas;

D O I：

10.1016/j.fuproc.2007.11.007

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The addition of small amount of TiO2 to silica-supported cobalt catalysts significantly increasing the dispersion of cobalt and Co metallic surface area resulting in the remarkable enhancement of the Fisher-Tropsch synthesis (FTS) activity in the slurry-pliase reaction. The addition of TiO2 adjusted the interaction between cobalt and silica support quite well to realize the favorite dispersion and reduction degree of supported cobalt, leading to high catalytic activity in FTS. The properties of various catalysts were characterized by in-situ DRIFT, XRD, TPR, N-2 physisorption and H-2 chemisorption. (c) 2007 Elsevier B.V. All rights reserved.

引用

页码：455 / 459

页数：5

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