Isolation of single crystals of a homoleptic UO22+-diglycolamide complex from a room temperature ionic liquid: X-ray crystallography and complexation studies

被引:11
作者
Ansari, Seraj A. [1 ]
Wadawale, Amey P. [2 ]
Verboom, Willem [3 ]
Mohapatra, Prasanta K. [1 ]
机构
[1] Bhabha Atom Res Ctr, Radiochem Div, Mumbai 400085, Maharashtra, India
[2] Bhabha Atom Res Ctr, Chem Div, Mumbai 400085, Maharashtra, India
[3] Univ Twente, MESA Inst Nanotechnol, Dept Mol & Mat, Mol Nanofabricat Grp, POB 217, NL-7500 AE Enschede, Netherlands
关键词
EXTRACTION; DIGLYCOLAMIDE; SOLVENTS; NITRATE; DIAMIDE; MEDIA;
D O I
10.1039/d1nj05760j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Complexation and structural investigations of the solid complex of UO22+ ions and N,N,N ',N '-tetramethyl diglycolamide isolated from a room temperature ionic liquid, for the first time, revealed that the nature and the structural features of the complex are identical to those of the complex isolated from an aqueous medium.
引用
收藏
页码:950 / 954
页数:5
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