Isolation of single crystals of a homoleptic UO22+-diglycolamide complex from a room temperature ionic liquid: X-ray crystallography and complexation studies

被引:11
作者
Ansari, Seraj A. [1 ]
Wadawale, Amey P. [2 ]
Verboom, Willem [3 ]
Mohapatra, Prasanta K. [1 ]
机构
[1] Bhabha Atom Res Ctr, Radiochem Div, Mumbai 400085, Maharashtra, India
[2] Bhabha Atom Res Ctr, Chem Div, Mumbai 400085, Maharashtra, India
[3] Univ Twente, MESA Inst Nanotechnol, Dept Mol & Mat, Mol Nanofabricat Grp, POB 217, NL-7500 AE Enschede, Netherlands
关键词
EXTRACTION; DIGLYCOLAMIDE; SOLVENTS; NITRATE; DIAMIDE; MEDIA;
D O I
10.1039/d1nj05760j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Complexation and structural investigations of the solid complex of UO22+ ions and N,N,N ',N '-tetramethyl diglycolamide isolated from a room temperature ionic liquid, for the first time, revealed that the nature and the structural features of the complex are identical to those of the complex isolated from an aqueous medium.
引用
收藏
页码:950 / 954
页数:5
相关论文
共 35 条
[1]   First Report on the Complexation of Uranyl Ion with Two Diglycolamide Ligands in a Room Temperature Ionic Liquid: Optical Spectroscopy and Calorimetric Studies [J].
Ansari, Seraj A. ;
Dumpala, Rama Mohana R. ;
Mohapatra, Prasanta K. .
CHEMISTRYSELECT, 2021, 6 (24) :6037-6042
[2]   Highly Efficient Extraction of Trivalent f-Cations Using Several N-Pivot Tripodal Diglycolamide Ligands in an Ionic Liquid: The Role of Ligand Structure on Metal Ion Complexation [J].
Ansari, Seraj A. ;
Mohapatra, Prasanta K. ;
Verma, Parveen K. ;
Leoncini, Andrea ;
Yadav, Ashok K. ;
Jha, Shambhu N. ;
Bhattacharyya, Dibyendu ;
Huskens, Jurriaan ;
Verboom, Willem .
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2020, 2020 (02) :191-199
[3]   Complexation thermodynamics of tetraalkyl diglycolamides with trivalent f-elements in ionic liquids: spectroscopic, microcalorimetric and computational studies [J].
Ansari, Seraj A. ;
Mohapatra, Prasanta K. ;
Ali, Sk. Musharaf ;
Rawat, Neetika ;
Tomar, Bhupinder S. ;
Leoncini, Andrea ;
Huskens, Jurriaan ;
Verboom, Willem .
NEW JOURNAL OF CHEMISTRY, 2018, 42 (01) :708-716
[4]   Chemistry of Diglycolamides: Promising Extractants for Actinide Partitioning [J].
Ansari, Seraj A. ;
Pathak, Priyanath ;
Mohapatra, Prasanta K. ;
Manchanda, Vijay K. .
CHEMICAL REVIEWS, 2012, 112 (03) :1751-1772
[5]  
Billard I., 2013, HDB PHYS CHEM RARE E
[6]   Lanthanides and actinides in ionic liquids [J].
Binnemans, Koen .
CHEMICAL REVIEWS, 2007, 107 (06) :2592-2614
[7]   Speciation of uranium(VI) extracted from acidic nitrate media by TODGA into molecular and ionic solvents [J].
Boltoeva, Maria ;
Gaillard, Clotilde ;
Georg, Sylvia ;
Karandashev, Vasilii K. ;
Turanov, Alexander N. .
SEPARATION AND PURIFICATION TECHNOLOGY, 2018, 203 :11-19
[8]   Solvent properties of the 1-butyl-3-methylimidazolium hexafluorophosphate ionic liquid [J].
Carda-Broch, S ;
Berthod, A ;
Armstrong, DW .
ANALYTICAL AND BIOANALYTICAL CHEMISTRY, 2003, 375 (02) :191-199
[9]   Crystallization of Uranyl Salts from Dialkylimidazolium Ionic Liquids or Their Precursors [J].
Cocalia, Violina ;
Smiglak, Marcin ;
Kelley, Steven P. ;
Shamshina, Julia L. ;
Gurau, Gabriela ;
Rogers, Robin D. .
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2010, (18) :2760-2767
[10]   Investigation of equilibria in solution. Determination of equilibrium constants with the HYPERQUAD suite of programs [J].
Gans, P ;
Sabatini, A ;
Vacca, A .
TALANTA, 1996, 43 (10) :1739-1753