Large macroscopic size changes in chemomechanical polymers with binding sites for metal ions

被引：15

作者：

Schneider, HJ ^{[1
]}

Liu, TJ

机构：

[1] Univ Saarland, FR Organ Chem, D-66041 Saarbrucken, Germany

[2] Univ Saarland, Inst Neue Mat, D-66041 Saarbrucken, Germany

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 01期

关键词：

D O I：

10.1039/b310939a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A flexible polymer based on the reaction of polyacrylate with diethylenetriamine shows, under the control of transition metal ions in the external aqueous medium, size expansion or contraction by up to 200% (corresponding to 400% volume change); the macroscopic movements, which are fully reversible, show a distinct maximum at a certain metal salt concentration, and vary significantly with the addition of second effector compounds such as sodium chloride or benzoate.

引用

页码：100 / 101

页数：2

共 50 条

[21] STUDY OF NATURE OF METAL-BINDING SITES AND ESTIMATE OF DISTANCE BETWEEN METAL-BINDING SITES IN TRANSFERRIN USING TRIVALENT LANTHANIDE IONS AS FLUORESCENT PROBES
LUK, CK
BIOCHEMISTRY, 1971, 10 (15) : 2838 - &
[22] CIRCULARLY POLARIZED LUMINESCENCE AS A PROBE OF METAL-IONS BINDING-SITES IN CALMODULIN
CORUH, N
RIEHL, JP
COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1991, 56 (12) : 3028 - 3031
[23] Characterizing divalent metal ion binding sites in graphene oxide with Mn(II) ions
Decker, Gerald
Nolasco, Lyle
Gesuelli, Kelly-Ann
Hirsh, Donald
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2016, 251
[24] Competition between heavy metal ions for binding sites in lichens: Implications for biomonitoring studies
Paoli, Luca
Vannini, Andrea
Monaci, Fabrizio
Loppi, Stefano
CHEMOSPHERE, 2018, 199 : 655 - 660
[25] PREFERENTIAL BINDING OF COPPER IONS TO SUPEROXIDE-DISMUTASE SUBUNITS LACKING METAL-IONS IN THE ZINC SITES
VIEZZOLI, MS
WANG, YJ
INORGANICA CHIMICA ACTA-BIOINORGANIC CHEMISTRY, 1988, 153 (03): : 189 - 191
[26] ELUCIDATION OF THE BINDING-SITES INVOLVED IN CHELATION OF METAL-IONS BY GALACTURONIC ACID
BAXTER, MA
SHUPACK, SI
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1989, 197 : 297 - INOR
[27] BINDING-SITES AND STABILITIES OF TRANSITION-METAL IONS WITH NUCLEOSIDES AND RELATED LIGANDS
KIM, SH
MARTIN, RB
INORGANICA CHIMICA ACTA-BIOINORGANIC CHEMISTRY, 1984, 91 (01): : 19 - 24
[28] Experimental localization of metal-binding sites reveals the role of metal ions in type II DNA topoisomerases
Wang, Beijia
Najmudin, Shabir
Pan, Xiao-Su
Mykhaylyk, Vitaliy
Orr, Christian
Wagner, Armin
Govada, Lata
Chayen, Naomi E.
Fisher, L. Mark
Sanderson, Mark R.
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2024, 121 (41)
[29] Kinetics of conformational changes induced by the binding of various metal ions to bovine α-lactalbumin
Noyelle, K
Van Dael, H
JOURNAL OF INORGANIC BIOCHEMISTRY, 2002, 88 (01) : 69 - 76
[30] Are the carboxyl groups of pectin polymers the only metal-binding sites in plant cell walls?
Nataly Meychik
Yuliya Nikolaeva
Maria Kushunina
Igor Yermakov
Plant and Soil, 2014, 381 : 25 - 34

← 1 2 3 4 5 →