Synthesis and characterization of highly porous borazine-linked polymers and their performance in hydrogen storage application

被引：55
作者：
Reich, Thomas E. [1 ]
Jackson, Karl T. [1 ]
Li, Sa [1 ]
Jena, Puru [1 ]
El-Kaderi, Hani M. [1 ]
机构：
[1] Virginia Commonwealth Univ, Dept Chem, Dept Phys, Richmond, VA 23284 USA
来源：
JOURNAL OF MATERIALS CHEMISTRY | 2011年 / 21卷 / 29期
关键词：
SURFACE-AREA; INTRINSIC MICROPOROSITY; RETICULAR SYNTHESIS; CRYSTALLINE; FRAMEWORK; NETWORKS;
D O I：
10.1039/c1jm11455g
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A new class of highly porous borazine-linked polymers (BLPs) has been synthesized utilizing arylamines and boron trihalides. BLPs exhibit Brunauer-Emmett-Teller (BET) surface areas in the range of 503 to 1364 m(2) g(-1) and store up to 1.3 wt% of hydrogen with 7.1 kJ mol(-1) isosteric heat of adsorption.
引用
收藏
页码：10629 / 10632
页数：4
相关论文
共 42 条
[1]  
Accelrys Inc., 2003, MAT STUD 4 3 V
[2]   ATROPISOMERISM IN ORTHO-ARYL-SUBSTITUTED BORAZINES [J].
ALLAOUD, S ;
ZAIR, T ;
KARIM, A ;
FRANGE, B .
INORGANIC CHEMISTRY, 1990, 29 (07) :1447-1449
[3]  
[Anonymous], EN EFF REN EN
[4]   On the mechanism of hydrogen storage in a metal-organic framework material [J].
Belof, Jonathan L. ;
Stern, Abraham C. ;
Eddaoudi, Mohamed ;
Space, Brian .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (49) :15202-15210
[5]   Targeted Synthesis of a Porous Aromatic Framework with High Stability and Exceptionally High Surface Area [J].
Ben, Teng ;
Ren, Hao ;
Ma, Shengqian ;
Cao, Dapeng ;
Lan, Jianhui ;
Jing, Xiaofei ;
Wang, Wenchuan ;
Xu, Jun ;
Deng, Feng ;
Simmons, Jason M. ;
Qiu, Shilun ;
Zhu, Guangshan .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (50) :9457-9460
[6]   Reticular synthesis of microporous and mesoporous 2D covalent organic frameworks [J].
Cote, Adrien P. ;
El-Kaderi, Hani M. ;
Furukawa, Hiroyasu ;
Hunt, Joseph R. ;
Yaghi, Omar M. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (43) :12914-+
[7]   Porous, crystalline, covalent organic frameworks [J].
Côté, AP ;
Benin, AI ;
Ockwig, NW ;
O'Keeffe, M ;
Matzger, AJ ;
Yaghi, OM .
SCIENCE, 2005, 310 (5751) :1166-1170
[8]   High Surface Area Conjugated Microporous Polymers: The Importance of Reaction Solvent Choice [J].
Dawson, Robert ;
Laybourn, Andrea ;
Khimyak, Yaroslav Z. ;
Adams, Dave J. ;
Cooper, Andrew I. .
MACROMOLECULES, 2010, 43 (20) :8524-8530
[9]   Polymers of Intrinsic Microporosity with Dinaphthyl and Thianthrene Segments [J].
Du, Naiying ;
Robertson, Gilles P. ;
Pinnau, Ingo ;
Guiver, Michael D. .
MACROMOLECULES, 2010, 43 (20) :8580-8587
[10]   Design of a series of preceramic B-tri(methylamino)borazine-based polymers as fiber precursors:: Shear rheology investigations [J].
Duperrier, Sylvain ;
Bernard, Samuel ;
Calin, Andreea ;
Sigala, Catherine ;
Chiriac, Rodica ;
Miele, Philippe ;
Balan, Corneliu .
MACROMOLECULES, 2007, 40 (04) :1028-1034
12345