SYNTHESIS, CHARACTERIZATION, AND ADSORPTION KINETIC STUDIES OF ETHYLENEDIAMINE MODIFIED CELLULOSE FOR REMOVAL OF Cd AND Pb

被引：40

作者：

Musyoka, Stephen Makali ^{[2
]}

Ngila, Jane Catherine ^{[1
,2
]}

Moodley, Brenda ^{[2
]}

Petrik, Lesley ^{[1
]}

Kindness, Andrew ^{[2
]}

机构：

[1] Univ Johannesburg, Dept Chem Technol, ZA-2028 Johannesburg, South Africa

[2] Univ Kwazulu Natal, Sch Chem, Durban, South Africa

来源：

ANALYTICAL LETTERS | 2011年 / 44卷 / 11期

关键词：

Adsorption kinetics; Ethylenediamine; Heavy metal removal; Langmuir isotherms; Modified cellulose; Surface functionalization; HEAVY-METAL IONS; WASTE-WATER; ABSORPTION; THERMODYNAMICS; EXTRACTANT; SORPTION; SAWDUST;

D O I：

10.1080/00032719.2010.539736

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Surface functionalization of cellulose using ethylenediamine was performed to improve its binding capacity for Cd and Pb. Adsorption kinetics at pH 6.0 and 25 degrees C revealed the Langmuir model to better describe the binding phenomena based on linear regression correlation coefficient (R-2) values of 0.998 and 0.986 with adsorption capacities of 0.0136 and 0.0179 mmol g(-1) for Cd and Pb, respectively, using raw cellulose and 0.128 and 0.242 mmol g(-1) with ethylenediamine-modified cellulose. The Freundlich model gave binding capacities of 2.32 x 10(-3) and 2.08 x 10(-3) mmol g(-1) for Cd and Pb, with R-2 values of 0.979 and 0.942, respectively.

引用

页码：1925 / 1936

页数：12

共 28 条

[1] Heavy metal ions removal by chelating resin [J].

Abd El-Moniem, NM ;

El-Sourougy, MR ;

Shaaban, DAF .

PIGMENT & RESIN TECHNOLOGY, 2005, 34 (06) :332-339

[2] Improved performance of a cellulose-based anion exchanger with tertiary amine functionality for the adsorption of chromium(VI) from aqueous solutions [J].

Anirudhan, T. S. ;

Jalajamony, S. ;

Suchithra, P. S. .

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2009, 335 (1-3) :107-113

[3] Heavy metal adsorption by modified oak sawdust: Thermodynamics and kinetics [J].

Argun, Mehmet Emin ;

Dursun, Sukru ;

Ozdemir, Celalettin ;

Karatas, Mustafa .

JOURNAL OF HAZARDOUS MATERIALS, 2007, 141 (01) :77-85

[4] Modification of rice hull and sawdust sorptive characteristics for remove heavy metals from synthetic solutions and wastewater [J].

Asadi, Fatemeh ;

Shariatmadari, Hossien ;

Mirghaffari, Noorallah .

JOURNAL OF HAZARDOUS MATERIALS, 2008, 154 (1-3) :451-458

[5] Succinate-bonded cellulose: A regenerable and powerful sorbent for cadmium-removal from spiked high-hardness groundwater [J].

Belhalfaoui, Belkacem ;

Aziz, Abdellah ;

Elandaloussi, El Hadj ;

Ouali, Mohand Said ;

De Menorval, Louis Charles .

JOURNAL OF HAZARDOUS MATERIALS, 2009, 169 (1-3) :831-837

[6]

CASTRO GR, 2004, MAT RES, V7, P329

[7] Preparation of ethylenediamine-anchored cellulose and determination of thermochemical data for the interaction between cations and basic centers at the solid/liquid interface [J].

da Silva Filho, Edson C. ;

de Melo, Julio C. P. ;

Airoldi, Claudio .

CARBOHYDRATE RESEARCH, 2006, 341 (17) :2842-2850

[8] Maleic anhydride incorporated onto cellulose and thermodynamics of cation-exchange process at the solid/liquid interface [J].

de Melo, Julio C. P. ;

da Silva Filho, Edson C. ;

Santana, Sirlane A. A. ;

Airoldi, Claudio .

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2009, 346 (1-3) :138-145

[9] Adsorption of heavy metal ions onto ethylene diamine-derived and Cibacron Blue F3GA-incorporated microporous poly(2-hydroxyethyl methacrylate) membranes [J].

Denizli, A ;

Say, R ;

Patir, S ;

Arica, MY .

REACTIVE & FUNCTIONAL POLYMERS, 2000, 43 (1-2) :17-24

[10] Electrospinning cellulose and cellulose derivatives [J].

Frey, Margaret W. .

POLYMER REVIEWS, 2008, 48 (02) :378-391

← 1 2 3 →