Conversion of Ethanol into Polyolefin Building Blocks: Reaction Pathways on Nickel Ion-loaded Mesoporous Silica

被引：43
作者：
Iwamoto, Masakazu [1 ]
Kasai, Kouji [1 ]
Haishi, Teruki [1 ]
机构：
[1] Tokyo Inst Technol, Chem Resources Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan
来源：
CHEMSUSCHEM | 2011年 / 4卷 / 08期
关键词：
ethanol; mesoporous silica; metathesis; nickel; propene; HIGHLY SELECTIVE CONVERSION; SOLID ACID CATALYSTS; HALIDE CLUSTERS; AQUEOUS-ETHANOL; EXCHANGE METHOD; HZSM-5; ZEOLITE; DEHYDRATION; TRANSFORMATION; ETHYLENE; ALCOHOLS;
D O I：
10.1002/cssc.201100168
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Ethanol to olefins: Very fast, selective, and stable formation of ethene, propene, and butenes from ethanol is achieved on Ni-MCM-41 at 573-723K, without deactivation. Two reaction pathways via diethyl ether and acetaldehyde are suggested. The results are relevant for the possible use of bioethanol as a renewable material for the production of plastics. © 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：1055 / 1058
页数：4
相关论文
共 38 条
  • [1] PREPARATION AND CHARACTERIZATION OF FE2O3 NANOPARTICLES IN MESOPOROUS SILICATE
    ABE, T
    TACHIBANA, Y
    UEMATSU, T
    IWAMOTO, M
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (16) : 1617 - 1618
  • [2] Study of operating variables in the transformation of aqueous ethanol into hydrocarbons on an HZSM-5 zeolite
    Aguayo, AT
    Gayubo, AG
    Tarrío, AM
    Atutxa, A
    Bilbao, J
    [J]. JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY, 2002, 77 (02) : 211 - 216
  • [3] Catalyst deactivation by coke in the transformation of aqueous ethanol into hydrocarbons. Kinetic modeling and acidity deterioration of the catalyst
    Aguayo, AT
    Gayubo, AG
    Atutxa, A
    Olazar, M
    Bilbao, J
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2002, 41 (17) : 4216 - 4224
  • [4] The transformation of ethanol over AlPO4 and SAPO molecular sieves with AEL and AFI topology. Kinetic and thermodynamic approach
    Arias, D
    Colmenares, A
    Cubeiro, ML
    Goldwasser, J
    Lopez, CM
    Machado, FJ
    Sazo, V
    [J]. CATALYSIS LETTERS, 1997, 45 (1-2) : 51 - 58
  • [5] Bakoyannakis DN, 2001, J CHEM TECHNOL BIOT, V76, P1159, DOI 10.1002/jctb.487.abs
  • [6] Dehydration of alcohols by microporous niobium silicate AM-11
    Brandao, P
    Philippou, A
    Rocha, J
    Anderson, MW
    [J]. CATALYSIS LETTERS, 2002, 80 (3-4) : 99 - 102
  • [7] Surface-treated activated carbons as catalysts for the dehydration and dehydrogenation reactions of ethanol
    Carrasco-Marín, F
    Mueden, A
    Moreno-Castilla, C
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (46): : 9239 - 9244
  • [8] Catalytic conversion of ethanol and iso-propanol over ZnO-treated Co3O4/Al2O3 solids
    Doheim, MM
    El-Shobaky, HG
    [J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2002, 204 (1-3) : 169 - 174
  • [9] Kinetic modelling for the transformation of bioethanol into olefins on a hydrothermally stable Ni-HZSM-5 catalyst considering the deactivation by coke
    Gayubo, Ana G.
    Alonso, Ainhoa
    Valle, Beatriz
    Aguayo, Andres T.
    Olazar, Martin
    Bilbao, Javier
    [J]. CHEMICAL ENGINEERING JOURNAL, 2011, 167 (01) : 262 - 277
  • [10] Kinetic Model for the Transformation of Bioethanol into Olefins over a HZSM-5 Zeolite Treated with Alkali
    Gayubo, Ana G.
    Alonso, Ainhoa
    Valle, Beatriz
    Aguayo, Andres T.
    Bilbao, Javier
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2010, 49 (21) : 10836 - 10844
1234