Electrochemical carboxylation of bicyclo[n.1.0]alkylidene derivatives

被引：27

作者：

Chowdhury, MA ^{[1
]}

Senboku, H ^{[1
]}

Tokuda, M ^{[1
]}

机构：

[1] Hokkaido Univ, Grad Sch Engn, Div Mol Chem, Organ Synth Lab, Sapporo, Hokkaido 0608628, Japan

来源：

TETRAHEDRON | 2004年 / 60卷 / 02期

基金：

日本学术振兴会;

关键词：

electrochemical carboxylation; bicyclo[n.1.0]alkylidene derivative; ring-fused alkylidenecyclopropane; carbon dioxide; carboxylic acid;

D O I：

10.1016/j.tet.2003.10.126

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Electrochemical carboxylation of bicyclo[n.1.0]alkylidene derivatives (ring-fused alkylidenecyclopropanes) in a suitable aprotic solvent using a one-compartment electrochemical cell equipped with a platinum plate cathode and a zinc plate anode under an atmospheric pressure of carbon dioxide afforded either mono- or dicarboxylic acid in moderate to good yields. (C) 2003 Elsevier Ltd. All rights reserved.

引用

页码：475 / 481

页数：7

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