Synthesis, structure and fluorescence of a zinc(II) chelate complex with bis(2,4,7,8,9-pentamethyldipyrrolylmethen-3-yl)methane

被引:39
作者
Berezin, Mikhail B. [1 ]
Antina, Elena V. [1 ]
Dudina, Natalia A. [1 ]
Bushmarinov, Ivan S. [2 ]
Antipin, Mikhail Yu. [2 ]
Antina, Lubov A. [1 ]
Guseva, Galina B. [1 ]
机构
[1] Russian Acad Sci, Inst Solut Chem, Ivanovo 153045, Russia
[2] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia
关键词
DONOR ENERGY MIGRATION; DYES; FLUOROIONOPHORE; 3,3'-POSITIONS; CHOLESTEROL; SWITCHES; DYNAMICS; (NIL)(2); LIGANDS; LIGHT;
D O I
10.1016/j.mencom.2011.04.020
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The crystal structure and spectral properties of new Zn(II) chelate complex with bis(2,4,7,8,9-pentamethyldipyrrolylmethen-3-yl)methane were determined by single-crystal X-ray diffraction, H-1 NMR, UV and 112 spectroscopy; a sufficiently high quantum yield of fluorescence in nonpolar solvents, a long-wavelength emission maximum and good photostability of the complex were demonstrated.
引用
收藏
页码:168 / 170
页数:3
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