Synthesis, structure and fluorescence of a zinc(II) chelate complex with bis(2,4,7,8,9-pentamethyldipyrrolylmethen-3-yl)methane

被引：39
作者：
Berezin, Mikhail B. [1 ]
Antina, Elena V. [1 ]
Dudina, Natalia A. [1 ]
Bushmarinov, Ivan S. [2 ]
Antipin, Mikhail Yu. [2 ]
Antina, Lubov A. [1 ]
Guseva, Galina B. [1 ]
机构：
[1] Russian Acad Sci, Inst Solut Chem, Ivanovo 153045, Russia
[2] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia
来源：
MENDELEEV COMMUNICATIONS | 2011年 / 21卷 / 03期
关键词：
DONOR ENERGY MIGRATION; DYES; FLUOROIONOPHORE; 3,3'-POSITIONS; CHOLESTEROL; SWITCHES; DYNAMICS; (NIL)(2); LIGANDS; LIGHT;
D O I：
10.1016/j.mencom.2011.04.020
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The crystal structure and spectral properties of new Zn(II) chelate complex with bis(2,4,7,8,9-pentamethyldipyrrolylmethen-3-yl)methane were determined by single-crystal X-ray diffraction, H-1 NMR, UV and 112 spectroscopy; a sufficiently high quantum yield of fluorescence in nonpolar solvents, a long-wavelength emission maximum and good photostability of the complex were demonstrated.
引用
收藏
页码：168 / 170
页数：3
相关论文
共 31 条
  • [1] ANTINA EV, 2009, 12 RES C YOUNG SCI O, P251
  • [2] ANTINA EV, 2009, 12 RES C YOUNG SCI O, P70
  • [3] Correlations between photophysics and lasing properties of dipyrromethene-BF2 dyes in solution
    Arbeloa, TL
    Arbeloa, FL
    Arbeloa, IL
    García-Moreno, I
    Costela, A
    Sastre, R
    Amat-Guerri, F
    [J]. CHEMICAL PHYSICS LETTERS, 1999, 299 (3-4) : 315 - 321
  • [4] The use of site-directed fluorophore labeling and donor-donor energy migration to investigate solution structure and dynamics in proteins
    Bergström, F
    Hägglöf, P
    Karolin, J
    Ny, T
    Johansson, LBÅ
    [J]. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1999, 96 (22) : 12477 - 12481
  • [5] A synthesis and proper-ties of new 4,4-difluoro-3a,4a-diaza-s-indacene (BODIPY)-labeled lipids
    Boldyrev, IA
    Molotkovsky, JG
    [J]. RUSSIAN JOURNAL OF BIOORGANIC CHEMISTRY, 2006, 32 (01) : 78 - 83
  • [6] New ON-OFF type Ca2+-selective fluoroionophore having boron-dipyrromethene fluorophores
    Cha, NR
    Moon, SY
    Chang, SK
    [J]. TETRAHEDRON LETTERS, 2003, 44 (45) : 8265 - 8268
  • [7] Ion sensing coupled to resonance energy transfer: A highly selective and sensitive ratiometric fluorescent chemosensor for Ag(I) by a modular approach
    Coskun, A
    Akkaya, EU
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (30) : 10464 - 10465
  • [8] DUDINA NA, 2009, 24 INT CHUG C COORD, P264
  • [9] The structure of a serpin-protease complex revealed by intramolecular distance measurements using donor-donor energy migration and mapping of interaction sites
    Fa, M
    Bergström, F
    Hägglöf, P
    Wilczynska, M
    Johansson, LBÄ
    Ny, T
    [J]. STRUCTURE WITH FOLDING & DESIGN, 2000, 8 (04): : 397 - 405
  • [10] Synthesis and properties of novel fluorescent switches
    Golovkova, TA
    Kozlov, DV
    Neckers, DC
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2005, 70 (14) : 5545 - 5549
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