An unexpected in situ formation of a substitute tetrazole ligand and its Mn(II) and Cu(II) complexes

被引：25
作者：
Mo, XH
Gao, EQ
He, Z
Li, WJ
Yan, CH [1 ]
机构：
[1] Peking Univ, Coll Chem, State Key Lab Rare Earth, Beijing 100871, Peoples R China
[2] Univ Sci & Technol Beijing, Dept Chem, Beijing 100083, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2004年 / 7卷 / 03期
基金：
中国国家自然科学基金;
关键词：
in situ formation; tetrazole; azide; hydrogen bond;
D O I：
10.1016/j.inoche.2003.12.013
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of 2-aminomethylpyridine, benzaldehyde and NaN3 in the presence of the metal ions leads to an unexpected in situ formation of a substituted tetrazole, 5-(2-pyridyl)-1H-tetrazole, and its Mn(II) and Cu(II) compounds MnL2(H2O)(2) (1) and CuL2(H2O)(2) (2). In these structures, mononuclear units connect each other via hydrogen bonds to form a two-dimensional network. (C) 2003 Elsevier B.V. All rights reserved.
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页码：353 / 355
页数：3
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