TADDOL-Derived Phosphonites, Phosphites, and Phosphoramidites in Asymmetric Catalysis

被引：65
作者：
Lam, Hon Wai [1 ]
机构：
[1] Univ Edinburgh, Sch Chem, Edinburgh EH9 3JJ, Midlothian, Scotland
来源：
SYNTHESIS-STUTTGART | 2011年 / 13期
关键词：
asymmetric catalysis; phosphorus; ligands; enantioselectivity; TADDOL; ENANTIOSELECTIVE CONJUGATE ADDITION; C BOND FORMATION; ALPHA; BETA-UNSATURATED CARBONYL-COMPOUNDS; CHIRAL PHOSPHORUS LIGANDS; CYCLIC MESO-ANHYDRIDES; KINETIC RESOLUTION; DIALKYLZINC REAGENTS; REDUCTIVE ALDOL; MONODENTATE PHOSPHORAMIDITE; ALKENYL ISOCYANATES;
D O I：
10.1055/s-0030-1260022
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
In metal-based asymmetric catalysis, desirable attributes for chiral ligands include low cost, simplicity of synthesis, and ease of variation to enable fine-tuning of a particular transformation. TADDOL-derived phosphonites, phosphites, and phosphoramidites constitute one family of chiral ligand that possesses these features. In recent times, these ligands have excelled in a wide range of catalytic asymmetric reactions. This review article summarizes progress in this area.
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页码：2011 / 2043
页数：33
相关论文
共 216 条
[71]   Catalytic carbophilic activation:: Catalysis by platinum and gold π acids [J].
Fuerstner, Alois ;
Davies, Paul W. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (19) :3410-3449
[72]  
Garner S.A., 2008, MODERN REDUCTION MET, P387
[73]   Enantioselective organocatalysis [J].
Gaunt, Matthew J. ;
Johansson, Carin C. C. ;
McNally, Andy ;
Vo, Ngoc T. .
DRUG DISCOVERY TODAY, 2007, 12 (1-2) :8-27
[74]   Transition metal-catalyzed C-H activation reactions: diastereoselectivity and enantioselectivity [J].
Giri, Ramesh ;
Shi, Bing-Feng ;
Engle, Keary M. ;
Maugel, Nathan ;
Yu, Jin-Quan .
CHEMICAL SOCIETY REVIEWS, 2009, 38 (11) :3242-3272
[75]   Quantifying steric effects of α-diimine ligands.: Oxidative addition of MeI to rhodium(I) and migratory insertion in rhodium(III) complexes [J].
Gonsalvi, L ;
Gaunt, JA ;
Adams, H ;
Castro, A ;
Sunley, GJ ;
Haynes, A .
ORGANOMETALLICS, 2003, 22 (05) :1047-1054
[76]   Steric and electronic effects on the reactivity of Rh and Ir complexes containing P-S, P-P, and P-O ligands. Implications for the effects of chelate ligands in catalysis [J].
Gonsalvi, L ;
Adams, H ;
Sunley, GJ ;
Ditzel, E ;
Haynes, A .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (45) :13597-13612
[77]   Relativistic effects in homogeneous gold catalysis [J].
Gorin, David J. ;
Toste, F. Dean .
NATURE, 2007, 446 (7134) :395-403
[78]   NICKEL-CATALYZED, CHLOROTRIALKYLSILANE-ASSISTED CONJUGATE ADDITION OF ALKENYLTRIBUTYLTIN REAGENTS TO ALPHA,BETA-UNSATURATED ALDEHYDES - EVIDENCE FOR A [1-((TRIALKYLSILYL)OXY)ALLYL]NICKEL(II) MECHANISM [J].
GRISSO, BA ;
JOHNSON, JR ;
MACKENZIE, PB .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (13) :5160-5165
[79]  
Guo JH, 1999, ANGEW CHEM INT EDIT, V38, P1755, DOI 10.1002/(SICI)1521-3773(19990614)38:12<1755::AID-ANIE1755>3.0.CO
[80]  
2-Q
3456789101112